Architecture of a Hybrid Mesoporous Chemosensor for Fe³⁺ by Covalent Coupling Bis-Schiff Base PMBA onto the CPTES-Functionalized SBA-15

Abstract

A novel hybrid mesoporous material PMBA-SBA was designed and synthesized by immobilizing bis-schiff base N,N‘-(1,4-phenylenedimethyli- dyne)bis(1,4-benzenediamine) (PMBA) within the channels of (γ-chloropropyl)triethoxysilicane (CPTES) modified SBA-15. TEM images of the hybrid materials illustrated the reservation of the hexagonal ordered mesoporous structure of SBA-15 after functionalization. The characteristic absorbance of the CN stretching vibration of the Schiff base was observed in the IR spectrum of the hybrid materials, indicating the successful immobilization of PMBA in the mesoporous composite, while the XPS spectra confirmed that the linkage of the PMBA molecule within the channels of CPTES-functionalized SBA-15 is realized by forming a covalent bond between amino and chloropropyl groups. This novel mesoporous material PMBA-SBA showed a high selectivity to Fe3+ ion, which results from a dramatic fluorescence quenching by the addition of Fe3+ ion upon the suspensions of PMBA-SBA. A good linearity between the fluorescence intensity of PMBA-SBA and the concentration of Fe3+ ion is constructed, which enables this hybrid martial as a fluorescence chemosensor for detecting the Fe3+ ion with a satisfactory detection limit of 1.98 × 10-6 M. Judged on the linear equation, the fluorescence quenching of the hybrid material by Fe3+ ion progresses by static quenching forming a nonfluorescence complex.

Mimicking tricks from nature with sensory organic–inorganic hybrid materials

“…36,37 Almost all the sensory hybrid materials cited here contain MCM-41 and SBA-15 mesoporous silicas as inorganic scaffoldings.…”

A nanostructured LUS-1 based organic–inorganic hybrid optical sensor for highly selective sensing of Fe3+ in water

“…The Literature survey reveals that only limited examples of such hybrid mesoporous chemosensors for Fe 3 þ have been reported [34][35][36].…”

Designing a smart fluorescence chemosensor within the tailored channel of mesoporous material for sensitively monitoring toxic heavy metal ions Pb(II)

“…In our previous work, we designed a fluorescent chemosensor by post-grafting ␥-chloropropyltriethoxy silicane [Cl-(CH 2 ) 3 -Si-(C 2 H 5 O) 3 , CPTES] on the inner surface of mesoporous silica SBA-15, and then coupling a Bis-schiff base N,N -(1,4-phenylenedimethylidyne)bis-1,4-benzenediamine (PMBA) onto the chloropropyl groups of CPTES based on the elimination reaction between CPTES and the terminal amino group of PMBA [35]. In the preparation, the active binding chloropropyl groups were preimmobilized on SBA-15 by cross-linking to the surface silanol groups, which dramatically increases the rigidity of inner surface of mesoporous material SBA-15, leading to quite different photophysical behavior of the resulting chemosensor.…”