This study deals with TBR (Tritium Breeding Ratio) performance of the four different types of molten salt (FLiBe, FLiNaK, FLiNaBe, FLiNaRb) which has four different Li-6 enrichment ratios (0%, 30%, 60%, 90%) Moreover, two different vacuum vessel materials (SiC composite and V4Cr4Ti alloy) have been used in ARC reactor geometry. In models with TBR ≥1.05, it has been desired to examine the sustainability of the tritium production of the reactor by removing the neutron multiplication layer from the design without using the toxic Beryllium element. The neutronic performance studies have been examined in OpenMC, which is an open-source Monte Carlo neutron and photon transport code. The TBR values of the different models obtained and the change of these values according to Li-6 enrichment were examined. Thus, in an ARC fusion reactor whose design studies are ongoing, different materials and design options, the performance of the reactor to provide sustainable tritium production will be examined, thus contributing to the literature and future studies.