1994
DOI: 10.1111/j.1365-2621.1994.tb02098.x
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Arabinogalactan as a potential furfural precursor in roasted coffee

Abstract: A fraction C1 which was very rich in polysaccharides and did not contain sucrose was isolated from high molecular weight water-soluble material obtained from green coffee. After roasting, furfural was identified in fraction CI by means of headspace-GUMS analysis. Roasting of the fraction C1 clearly affected the arabinogalactan promoting a high loss of arabinose residues. We suggest that furfural found in fraction C1 originates mainly from arabinogalactan, which, together with sucrose appears to be the major fu… Show more

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Cited by 10 publications
(4 citation statements)
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“…The melanoidin fractions enriched with AGPs (Et75 and EtSn) obtained in the AGPCoffee model were the brownest, which is in agreement with Bekedam et al 16 The influence of AGPs on coffee color might be related to the reactivity of the arabinose side chains, as they are predominantly lost during the roasting process 16,17,31,49,55 and can form furfural in high yield, which, together with sucrose, appears to be the major furfural precursor in roasted coffee. 61 The arabinose, combined with the protein moiety of the AGPs, can yield powerful colorants. 62 Nevertheless, even in the AGPCoffee model, the Et50 accounted for nearly 30% of the HMWM brown color, and in the original, control, and SucCoffee accounted for, on average, 47% of the HMWM brown color.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…The melanoidin fractions enriched with AGPs (Et75 and EtSn) obtained in the AGPCoffee model were the brownest, which is in agreement with Bekedam et al 16 The influence of AGPs on coffee color might be related to the reactivity of the arabinose side chains, as they are predominantly lost during the roasting process 16,17,31,49,55 and can form furfural in high yield, which, together with sucrose, appears to be the major furfural precursor in roasted coffee. 61 The arabinose, combined with the protein moiety of the AGPs, can yield powerful colorants. 62 Nevertheless, even in the AGPCoffee model, the Et50 accounted for nearly 30% of the HMWM brown color, and in the original, control, and SucCoffee accounted for, on average, 47% of the HMWM brown color.…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…The spent coffee grounds are rich in non-solubilized polysaccharides such as galactomannans, arabinogalactans, and cellulose, with half of the total being in the form of galactomannans [3][4][5]. Currently, thermal hydrolysis processes are used industrially to increase the extraction of polysaccharides, but these processes have high energy consumption and generate undesirable compounds that negatively impact the taste of the beverage [6]. A more eco-friendly and sustainable potential strategy for the hydrolysis and solubilization of coffee polysaccharides is to use an enzymatic route, since enzymes act under moderate process conditions and are highly specific.…”
Section: Introductionmentioning
confidence: 99%
“…In contrast, contents of 2‐furancarboxaldehyde (or furfural) and 5‐methyl‐2‐furancarboxaldehyde, which have been reported as key volatile compounds contributing to sweet, caramel and almond notes (see Table 1) and were found in higher concentrations in roasted Arabica beans (Caporaso et al ., 2018), were significantly higher in SHS‐roasted beans, especially those prepared at higher temperatures. Since both furans are mainly formed either solely by caramelization or jointly with the Maillard reaction and are more rapidly formed than the three former furans at the same temperatures (Maria et al ., 1994; Ozolina et al ., 2011; Srivastava et al ., 2018), SHS roasting, which exhibited higher heating rates and resulted in more extensive formation of sugars as reported by Chindapan et al . (2019), accelerated their formation.…”
Section: Resultsmentioning
confidence: 99%