The hydrochemical characteristics of groundwater in Yenagoa and environs was investigated to determine the areal distribution of geochemical parameters and attempt to explain the controlling processes responsible for the various facies. Sixty water samples were collected from wells ( Borehole) at different times in both the dry season ( December to February) and the raining/wet Season ( Between May and October) and were analyzed for various parameters including pH, total dissolved solids (TDS), potassium (K), Sodium (Na), Calcium (Ca), Magnesium (Mg), Chlorine (Cl), Bicarbonate (HCO 3 ) and sulphate ion (SO4 2-) after standard procedures. The Data obtained from the laboratory analysis were used as variable inputs for the descriptive statistics such as mean, minimum, maximum and standard deviation. Laboratory tests were carried out on representative soil samples in accordance with British Standards (B.S) 1377, which are equivalent to the American Society of Testing Materials (ASTM) standards. The tests were grain size distribution analysis, permeability (using the constant and falling head permeameters) and Atterberg (consistency) limits and was conducted to enable the evaluation of the gradation, hydraulic conductivity (coefficient of permeability/ and consistency (water absorbing and adsorbing ability) properties of the soil samples, as well as their classification. Results showed that water table was generally close to the surface of the area. The first 0 to 5cm depth consist of organic clay, and essentially, the area is mostly characterized by the sandyclay and silty-clay materials. By implication, the upper clay protective layer for groundwater is thin, coupled with organic materials, biochemical oxygen demand is enhanced. Permeability and transmissivity character of the borehole indicate that if surface water is polluted in one area it can easily get transferred to other part of Yenagoa thus causing serious concern for health implication. The physico-chemical character of the groundwater reflects the hydrochemical facie of the groundwater in the study area. The most prevalent ionic concentration includes iron, calcium, magnesium, Sodium, potassium, chloride, and bicarbonate. The trend of occurrence shows the following relationship: Ca > HCO 3 > Na + > K > Mg > Cl -> SO 4 2 . Na + > K > Cl -. There is elevated occurrence of Ca 2+ > HCO 3 -> Mg 2+ ions in the groundwater beyond permissible level reflecting processes of natural rainwater recharge and water -soil/rock interaction