Aqueous solutions of non-ionic surfactant mixtures as mediums for green extraction of polyphenols from red grape pomace

Krstonošić, Milica Atanacković; Sazdanić, Darija; Ćirin, Dejan; Maravić, Nikola; Mikulić, Marina; Cvejić, Jelena; Krstonošić, Velјko

doi:10.1016/j.scp.2023.101069

Cited by 6 publications

(1 citation statement)

References 59 publications

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“…The application of micellar systems (monocomponent and multicomponent) in pharmaceutical and food formulations is largely based on the micellar solubilization of poorly soluble (hydrophobic) particles in water. − If poorly soluble particles do not have polar groups or have an insufficient number of polar groups, they are incorporated into the hydrophobic core of the micelle (in contrast, if they have sufficient polar groups, they are located near the polar groups of surfactants with which they build hydrogen, dipole–dipole, and ion–dipole interactions, depending on whether the surfactants are ionic or nonionic). − …”

Section: Introductionmentioning

confidence: 99%

Binary Mixed Micelles of Hexadecyltrimethylammonium Bromide–Sodium Deoxycholate and Dodecyltrimethylammonium Bromide–Sodium Deoxycholate: Thermodynamic Stabilization and Mixed Micelle Solubilization Capacity of Daidzein (Isoflavonoid)

Kumar,

Farkaš Agatić,

Popović

et al. 2024

Ind. Eng. Chem. Res.

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In this paper, the thermodynamic properties of binary mixtures of the surfactants hexadecyltrimethylammonium bromide (HA)−sodium deoxycholate (DC) and dodecyltrimethylammonium bromide (DA)−sodium deoxycholate (DC) in an aqueous NaCl solution (0.3 mol kg −1 ) in the temperature interval T = 273.1−323.1 K are examined. In binary mixed micelles such as HA−DC and DA−DC, there are synergistic interactions between structurally different micellar building units. The dependence of the molar excess Gibbs free energy of the formation of the binary mixed micellar pseudophase on the micellar molar fractions of the surfactants (g E = f(x i )) is a symmetric function (a first-order Margules function) where the molar excess entropy is not zero, i.e., the strict theory of regular mixtures does not apply. If the phenomenon of enthalpy−entropy compensation is valid for each partial thermodynamic process during the formation of a binary mixed micellar pseudophase (at a constant temperature) and there is an interval of surfactant mole fraction from the initial binary mixture, where each ratio between the enthalpy of a certain partial thermodynamic process and the RST enthalpy is constant, then the function g E = f(x i ) is a symmetric function. Both of the investigated binary micellar pseudophases in the solubilization of daidzein (D) exhibit synergistic solubilization in relation to the micellar solubilization of D with a system of monocomponent surfactants. The molar excess Gibbs free energies of D micellar solubilization with the mixed micelles HA−DC and DA−DC are negative, which means that binary mixed micellar pseudophases with the solubilizate D are more thermodynamically stable than systems with monocomponent micellar pseudophases containing solubilizate D.

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Section: Introductionmentioning

confidence: 99%

Binary Mixed Micelles of Hexadecyltrimethylammonium Bromide–Sodium Deoxycholate and Dodecyltrimethylammonium Bromide–Sodium Deoxycholate: Thermodynamic Stabilization and Mixed Micelle Solubilization Capacity of Daidzein (Isoflavonoid)

Kumar,

Farkaš Agatić,

Popović

et al. 2024

Ind. Eng. Chem. Res.

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Strategies for bioactive compound recovery from grape and apple wastes: traditional and emerging technologies to reach zero waste discharge

Sette,

Mattson,

Schebor

et al. 2024

Biomass Conv. Bioref.

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Extraction of Phenolic Compounds from Tucuma (Astrocaryum vulgare Mat.) Postprocessing Cake Mediated by Rhamnolipids: Evaluation of Its Antifungal Potential against Common Fruit Pathogens

Mota,

Santos,

Rocha

et al. 2024

ACS Food Sci. Technol.

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Tucuma is a native Amazon palm strategic to the local economy due to its pulp and kernel oil utilization and its possibility to be used in the recovery of degraded areas. The oil extraction generates a postpressing cake with potential industrial utilization. The utilization of this residue to generate new products is an opportunity to expand the market of the fruit, aiming at an almost zero waste industrial plant; moreover, it also helps to boost the local bioeconomy. The present work aims to evaluate the hydroethanolic extraction of phenolic compounds, with and without surfactant addition, from the tucuma pulp postpressing cake. For this, the hydroethanolic extraction was carried out at 62 °C, a solid:liquid ratio of 1:13, and an ethanol concentration equal to 54%; at this condition two rhamnolipid (RML) type surfactants, one with a majority of mono-RML and the other with a majority of di-RML, was added. The hydroethanolic extraction without RML presented catechin, epicatechin, and epigallocatechin. The addition of the RMLs in the extraction media modulates the phenolic compounds extracted and their quantities due to the relationship between the polarity of the phenolic compound (Log P) and the hydrophilic–lipophilic balance (HLB) of RMLs. The addition of mono-RML (HLB = 7.0) shifts the polarity of the system and enables the extraction of more hydrophobic compounds (epigallocatechin gallate, p-hydroxybenzoic acid, and 3,4-dihydroxybenzoic acid) and catechin. The di-RML hydroethanolic extract (HLB = 9.0) was the one with the highest number of compounds (catechin, epigallocatechin gallate, epicatechin, epigallocatechin, and p-hydroxybenzoic acid). This is probably due to the higher surfactant HLB and the proportion of mono/di-RML. The antifungal capacity of the extracts against fungi that cause postharvest rot in oranges and strawberries was also evaluated. Both mono-RML and di-RML hydroethanolic extracts presented higher inhibitory activity than the sole hydroethanolic extract or the sole RML, when evaluated against rot fungi. The RML extracts antifungal activity is probably due to the synergism between the phenolic compounds and RML. This is the first time that different RML congeners have been evaluated to extract different categories of phenolic compounds with different fungicidal actions.

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Aqueous solutions of non-ionic surfactant mixtures as mediums for green extraction of polyphenols from red grape pomace

Cited by 6 publications

References 59 publications

Binary Mixed Micelles of Hexadecyltrimethylammonium Bromide–Sodium Deoxycholate and Dodecyltrimethylammonium Bromide–Sodium Deoxycholate: Thermodynamic Stabilization and Mixed Micelle Solubilization Capacity of Daidzein (Isoflavonoid)

Binary Mixed Micelles of Hexadecyltrimethylammonium Bromide–Sodium Deoxycholate and Dodecyltrimethylammonium Bromide–Sodium Deoxycholate: Thermodynamic Stabilization and Mixed Micelle Solubilization Capacity of Daidzein (Isoflavonoid)

Strategies for bioactive compound recovery from grape and apple wastes: traditional and emerging technologies to reach zero waste discharge

Extraction of Phenolic Compounds from Tucuma (Astrocaryum vulgare Mat.) Postprocessing Cake Mediated by Rhamnolipids: Evaluation of Its Antifungal Potential against Common Fruit Pathogens

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