Abstract:Autoxidation is a widely recognized mechanism known to initiate the degradation of food and lipids and modify organic matter in the atmosphere. Given the low NOx concentration in aqueous media (e.g., cloud water and fog droplets), autoxidation can become vital to facilitate the formation of highly oxygenated molecules such as organic peroxides (ROOH and ROOR). Here, we have identified aqueous-phase autoxidation-initiated hydroperoxides in varying organic precursors, including a laboratory model compound and mo… Show more
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