Aquabis(3-fluorobenzoato-κO)(1,10-phenanthroline-κ²N,N′)copper(II)

Abstract

Key indicators: single-crystal X-ray study; T = 295 K; mean (C-C) = 0.006 Å; R factor = 0.046; wR factor = 0.132; data-to-parameter ratio = 12.2.In the title compound, [Cu(C 7 H 4

Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cobalt(II)

“…Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT (Bruker, 2005); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL. In recent years, the design and synthesis of metal complexes based on 3-fluorobenzoic acid have attracted much attention (Sevryugina et al, 2007;Motokawa et al, 2008;Wein et al, 2009;Yin, 2011;Miyasaka et al, 2011). We report herein the crystal structure of the title compound (I) ( Fig.…”