Applications of multifunctional metal–organic frameworks in perovskite photovoltaics: roles, advantages and prospects

Liu, Ming-Wu; Liu, Gengling; Wang, Yu-Fen; Lei, Bing-Xin; Wu, Wu-Qiang

doi:10.1039/d3qm01001e

Cited by 3 publications

(1 citation statement)

References 27 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The choice of these MOFs over alternatives is further justified by the general advantages of MOFs in PSCs, such as enhanced charge-extraction efficiency, inhibition of charge recombination, and improved layer quality, all of which contribute to increased device stability. The tunable porous nanostructures and desirable chemical absorption characteristics of MOFs like Cu-BTC and Co-BTC play a beneficial role in constructing high-performance and eco-friendly PSCs 23 .…”

Section: Introductionmentioning

confidence: 99%

Impact of copper and cobalt-based metal-organic framework materials on the performance and stability of hole-transfer layer (HTL)-free perovskite solar cells and carbon-based

Arjmand,

Rashidi Ranjbar

2024

Sci Rep

View full text Add to dashboard Cite

This article investigates the impact of metal-organic frameworks (MOFs) on the performance and stability of perovskite solar cells (PSCs), specifically focusing on the type of metal and the morphology of the MOF. Two types of MOFs, copper-benzene-1,3,5-tricarboxylate (Cu-BTC MOF) with spherical morphology and cobalt-benzene-1,3,5-tricarboxylate (Co-BTC MOF) with rod morphology, are synthesized and spin-coated on TiO2 substrates to form FTO/TiO2/MOF/CH3NH3PbI3/C-paste PSCs. The morphology and size of the MOFs are characterized by scanning electron microscopy (SEM), and the crystallinity and residual PbI2 of the perovskite films are analyzed by X-ray diffraction (XRD). The results show that the Co-BTC MOF PSC exhibits the highest power conversion efficiency (PCE) of 10.4% and the best stability, retaining 82% of its initial PCE after 264 h of storage in ambient air. The improved performance and stability are attributed to the enhanced crystallinity and reduced residual PbI2 of the perovskite film after Co-BTC MOF modification. The paper showcases the immense potential of MOF-based interlayers to revolutionize PSC technology, offering a path toward next-generation solar cells with enhanced performance and longevity.

show abstract

Section: Introductionmentioning

confidence: 99%

Impact of copper and cobalt-based metal-organic framework materials on the performance and stability of hole-transfer layer (HTL)-free perovskite solar cells and carbon-based

Arjmand,

Rashidi Ranjbar

2024

Sci Rep

View full text Add to dashboard Cite

show abstract

Recent Progress and Future Prospects of Metal‐Organic Frameworks for Adsorption, Separation and Catalytic Removal of NO_x and N₂O

Liu,

Zhang,

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

Nitrogen oxides (NOx) are produced during the high‐temperature combustion process of fossil fuels, which are considered as an atmospheric pollutant that can lead to significant environmental issues such as acid rain and photochemical smog. Therefore, it is essential to minimize the concentration of NOx in the atmosphere in order to protect the ecological environment upon which human beings depends. The integrated utilization of NOx removal technology results in environmentally harmless compounds, such as N2 and H2O, through the processes like adsorption, separation, catalytic reduction and other methods. Metal‐organic frameworks (MOFs) are seen as ideal candidates for addressing NOx pollution issues in the atmosphere due to their high specific surface area, ultrahigh porosity and unlimited modifiability. Herein, the latest research progress in MOFs and MOFs‐derived materials related to NOx adsorption, separation and catalytic reduction is presented and summarized. Besides, some opportunities and problems need to be solved in this field are proposed and discussed.

show abstract

A comprehensive review of organic frameworks: From synthesis to perovskite solar cells fabrication

Wu,

Liang,

Zhou

et al. 2024

Organic Electronics

View full text Add to dashboard Cite

Applications of multifunctional metal–organic frameworks in perovskite photovoltaics: roles, advantages and prospects

Abstract: Metal-organic frameworks (MOFs) are considered to be highly fascinating materials due to their excellent photoelectric properties, tunable porous nanostructures and desirable chemical absorption characteristics, which play beneficial roles in constructing...

Cited by 3 publications

References 27 publications

Impact of copper and cobalt-based metal-organic framework materials on the performance and stability of hole-transfer layer (HTL)-free perovskite solar cells and carbon-based

Impact of copper and cobalt-based metal-organic framework materials on the performance and stability of hole-transfer layer (HTL)-free perovskite solar cells and carbon-based

Recent Progress and Future Prospects of Metal‐Organic Frameworks for Adsorption, Separation and Catalytic Removal of NO_x and N₂O

A comprehensive review of organic frameworks: From synthesis to perovskite solar cells fabrication

Contact Info

Product

Resources

About

Applications of multifunctional metal–organic frameworks in perovskite photovoltaics: roles, advantages and prospects

Abstract: Metal-organic frameworks (MOFs) are considered to be highly fascinating materials due to their excellent photoelectric properties, tunable porous nanostructures and desirable chemical absorption characteristics, which play beneficial roles in constructing...

Cited by 3 publications

References 27 publications

Impact of copper and cobalt-based metal-organic framework materials on the performance and stability of hole-transfer layer (HTL)-free perovskite solar cells and carbon-based

Impact of copper and cobalt-based metal-organic framework materials on the performance and stability of hole-transfer layer (HTL)-free perovskite solar cells and carbon-based

Recent Progress and Future Prospects of Metal‐Organic Frameworks for Adsorption, Separation and Catalytic Removal of NOx and N2O

A comprehensive review of organic frameworks: From synthesis to perovskite solar cells fabrication

Contact Info

Product

Resources

About

Recent Progress and Future Prospects of Metal‐Organic Frameworks for Adsorption, Separation and Catalytic Removal of NO_x and N₂O