Application of UHPLC-MS/MS method to study occurrence and fate of sulfonamide antibiotics and their transformation products in surface water in highly urbanized areas

Kokoszka, Klaudia; Wilk, Joanna; Felis, Ewa; Bajkacz, Sylwia

doi:10.1016/j.chemosphere.2021.131189

Cited by 40 publications

(28 citation statements)

References 40 publications

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“…Due to high analyte loss, WCX and C18 as pre-columns in tandem SPE were not used. The employment of strong anion exchange sorbents (SAX/MAX) and/or HLB for the extraction of FCs from solid samples has been extensively reported [ 21 , 32 ] and promotes the separation of analytes in good recoveries. In our study, we also tested the feasibility of MAX and HLB sorbents.…”

Section: Resultsmentioning

confidence: 99%

“…According to IDA criteria, if a compound’s signal intensity exceeded 500 cps and was in the range of 100–1500 Da, then EPI mode was activated and the full mass spectrum recorded. Confirmation was obtained through comparison of the obtained mass spectra of TPs with those available in the literature [ 20 , 21 ]. The use of p-MRM-IDA-EPI reduced the amount of data obtained in the next step.…”

Section: Methodsmentioning

confidence: 99%

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Uptake of Pharmaceutical Pollutants and Their Metabolites from Soil Fertilized with Manure to Parsley Tissues

et al. 2022

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Manure is a major source of soil and plant contamination with veterinary drugs residues. The aim of this study was to evaluate the uptake of 14 veterinary pharmaceuticals by parsley from soil fertilized with manure. Pharmaceutical content was determined in roots and leaves. Liquid chromatography coupled with tandem mass spectrometry was used for targeted analysis. Screening analysis was performed to identify transformation products in the parsley tissues. A solid-liquid extraction procedure was developed combined with solid-phase extraction, providing recoveries of 61.9–97.1% for leaves and 51.7–95.6% for roots. Four analytes were detected in parsley: enrofloxacin, tylosin, sulfamethoxazole, and doxycycline. Enrofloxacin was detected at the highest concentrations (13.4–26.3 ng g−1). Doxycycline accumulated mainly in the roots, tylosin in the leaves, and sulfamethoxazole was found in both tissues. 14 transformation products were identified and their distribution were determined. This study provides important data on the uptake and transformation of pharmaceuticals in plant tissues.

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Section: Resultsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Uptake of Pharmaceutical Pollutants and Their Metabolites from Soil Fertilized with Manure to Parsley Tissues

et al. 2022

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“…Most veterinary antibiotics are not completely adsorbed in the animal intestines. The unabsorbed parts are transmitted into the environment in the form of prototypes and metabolites [ 4 , 5 ] through runoff [ 6 , 7 ], leaching, and manure used in the land [ 8 ], and eventually, they become the selection factor of resistant bacteria and multiple resistant bacteria [ 9 ]. Along with the overuse and abuse of antibiotics in recent years, antibiotic residues in the environment have caused continuous environmental pollution.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of the Magnetically Nanoporous Organic Polymer Fe₃O₄@SiO₂‐NH₂‐COP and Its Application in the Determination of Sulfonamide Residues in Surface Water Surrounding a Cattle Farm

Yang

Miao

Yin

et al. 2022

Bioinorganic Chemistry and Applications

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Efficient extractions of trace antibiotic residues in the environment are a key factor for accurate quantification of the residues. A new nanoporous material, namely, magnetically covalent organic polymer (MCOP, Fe3O4@SiO2-NH2-COP) was synthesized in this work and was used for magnetic solid-phase extraction (MSPE). The combination of MSPE with high-performance liquid chromatography separation together with ultraviolet detection (HPLC-UV) was established as an effective method for the determination of four sulfonamide (SA) residues in surface water surrounding a cattle farm. The synthesized magnetic material was characterized by SEM, TEM, FT-IR, magnetic properties measurement system (MPMS), and nitrogen gas porosimetry. The material possessed many attractive features, such as a unique microporous structure, a larger specific surface area (137.93 m2·g−1) than bare Fe3O4 (24.84 m2·g−1), high saturation magnetization (50.5 emu·g−1), open adsorption sites, and high stability. The influencing parameters, including pH, the used amount of MCOPs, the type of eluent, adsorption solution, and desorption time, were optimized. Under the optimized conditions, the method conferred good linearity ranges (R2 ≥ 0.9990), low detection limits (S/N = 3, LOD, 0.10–0.25 μg·L−1), and satisfactory recoveries (79.7% to 92.2%). The enrichment factor (EF) for the four SAs was 34.13–38.86. The relative standard deviations of intraday (n = 5) and of interday (n = 3) were less than 4.8% and 8.9%, respectively. The equilibria between extraction and desorption for SAs could be reached within 150 s. The proposed method was sensitive and convenient for detecting SA residues in complex environmental matrices, and the successful application of the new MCOPs as an adsorbent was demonstrated.

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“…The selected carbon powders were used as-prepared and after the immobilization of iron using two different protocols. Two wide spread used antibiotics frequently detected in water environments (metronidazole [32] and sulfamethoxazole [33]) were selected as the target pollutants to perform their degradation via the different electrochemical treatments both in synthetic water and in a real wastewater treatment plant effluent. The electrocatalytic performance of the process incorporating low-cost carbon-based cathodes has been analyzed in terms of degradation efficiency of the pollutants, energy consumption compared to typical carbon cathodes and reusability of the electrodes in subsequent cycles.…”

Section: Introductionmentioning

confidence: 99%

Exploring the use of carbon materials as cathodes in electrochemical advanced oxidation processes for the degradation of antibiotics

Poza-Nogueiras¹,

Gomis‐Berenguer²,

Pazos³

et al. 2022

Journal of Environmental Chemical Engineering

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Application of UHPLC-MS/MS method to study occurrence and fate of sulfonamide antibiotics and their transformation products in surface water in highly urbanized areas

Cited by 40 publications

References 40 publications

Uptake of Pharmaceutical Pollutants and Their Metabolites from Soil Fertilized with Manure to Parsley Tissues

Uptake of Pharmaceutical Pollutants and Their Metabolites from Soil Fertilized with Manure to Parsley Tissues

Synthesis of the Magnetically Nanoporous Organic Polymer Fe₃O₄@SiO₂‐NH₂‐COP and Its Application in the Determination of Sulfonamide Residues in Surface Water Surrounding a Cattle Farm

Exploring the use of carbon materials as cathodes in electrochemical advanced oxidation processes for the degradation of antibiotics

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Application of UHPLC-MS/MS method to study occurrence and fate of sulfonamide antibiotics and their transformation products in surface water in highly urbanized areas

Cited by 40 publications

References 40 publications

Uptake of Pharmaceutical Pollutants and Their Metabolites from Soil Fertilized with Manure to Parsley Tissues

Uptake of Pharmaceutical Pollutants and Their Metabolites from Soil Fertilized with Manure to Parsley Tissues

Synthesis of the Magnetically Nanoporous Organic Polymer Fe3O4@SiO2‐NH2‐COP and Its Application in the Determination of Sulfonamide Residues in Surface Water Surrounding a Cattle Farm

Exploring the use of carbon materials as cathodes in electrochemical advanced oxidation processes for the degradation of antibiotics

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Synthesis of the Magnetically Nanoporous Organic Polymer Fe₃O₄@SiO₂‐NH₂‐COP and Its Application in the Determination of Sulfonamide Residues in Surface Water Surrounding a Cattle Farm