Application of the NOE experiment to the analysis of boron hydride derivatives: confirming the assignments of the pseudocloso-complex [1,2-Ph2-3-{Cp*}-3,1,2-IrC2B9H9] (Cp*=η5-C5Me5) and the closo-compounds 1-Ph-1,2-C2B10H11 and 1-Ph-2-Me-1,2-C2B10H10

Reed, David; Welch, Alan J.; Cowie, Jill; Donohoe, David J.; Parkinson, John

doi:10.1016/s0020-1693(99)00062-6

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Metallaheteroboranes1

Iridium(iii)1

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Cited by 14 publications

(2 citation statements)

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“…89 The application of NOE in the analysis of carboranes and metallacarboranes has been reported. 90 The reactions of rhodathiaborane [8,8-(PPh 3 ) 2 -nido-8,7-RhSB 9 H 10 ] with bidentate phosphines (dppm, dppe and dppp) have been reported to result in complete substitution of the triphenylphosphine to afford a variety of complexes, depending on the stoichiometry of phosphine to thiaborane used. 91 A study into the competitive extraction of selected bases by the carbollylcobaltate anion from aqueous solution has been described.…”

Section: Metallaheteroboranesmentioning

confidence: 99%

3 Boron

Weller

2000

Annu. Rep. Prog. Chem., Sect. A

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Section: Metallaheteroboranesmentioning

confidence: 99%

3 Boron

Weller

2000

Annu. Rep. Prog. Chem., Sect. A

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“…173 177 The value of NOE effects in elucidating metalloborane NMR spectra was shown clearly in a study of [Ir(Cp*)(Ph 2 C 2 B 9 H 9 )]. 178 New iridium(III) complexes containing two cyclometallated 2-phenylpyridines and a bidentate terpy represent a new class of luminescent complex whose photophysical properties can be tuned by substituents in the 4 H position of terpy, which may also be used as the basis for more synthetic chemistry. 182…”

Section: Iridium(iii)mentioning

confidence: 99%

16 The noble metals

Thornton¹

2000

Annu. Rep. Prog. Chem., Sect. A

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Characterization of Persistent Intramolecular C‐H⋅⋅⋅X(N,O) Bonds in Solid State and Solution

Cappelli

Giorgi

Anzini

et al. 2004

Chemistry A European J

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The formation of intramolecular CH...X(N,O) bonds and their persistence in solution were studied by X-ray crystallography and NMR techniques in two different rotamers of a molecule containing the ortho-carborane cage, an amide group and a quinoline ring. Experimental data were confirmed by theoretical ab initio calculations. From the resolved structure of the two forms of this potentially active drug for boron neutron capture therapy, accurate bonding and geometric parameters were extracted for this non-classic hydrogen interaction, and their strength was calculated. These findings provided new insight in the theory of CH...X bonds, which appear stronger and less rare than it was previously thought.

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Application of the NOE experiment to the analysis of boron hydride derivatives: confirming the assignments of the pseudocloso-complex [1,2-Ph2-3-{Cp}-3,1,2-IrC2B9H9] (Cp=η5-C5Me5) and the closo-compounds 1-Ph-1,2-C2B10H11 and 1-Ph-2-Me-1,2-C2B10H10

Cited by 14 publications

References 10 publications

3 Boron

3 Boron

16 The noble metals

Characterization of Persistent Intramolecular C‐H⋅⋅⋅X(N,O) Bonds in Solid State and Solution

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