Application of the nitrosoamide reaction to hydrazones

McGirk, Richard H.; Cyr, Clifford R.; Ellis, William D.; White, Emil H.

doi:10.1021/jo00940a011

Search citation statements

Order By: Relevance

Paper Sections

Select...

Geminal Diazides1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1975

2017

Publication Types

Select...

Article6

Book1

Relationship

Self Cite0

Independent7

Authors

Journals

Cited by 9 publications

(2 citation statements)

References 5 publications

(6 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…There is only a limited number of publications that focus on the reactivity of geminal aliphatic diazides 21 . In most reports, diazides 21 are only mentioned as by-products or proposed intermediates [31,34,35,47,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79]. A few reports discuss thermodynamic and kinetic influences of the azido group on the stability of carbocations [80,81,82,83] and calculated structures of geminal diazides [84].…”

Section: Geminal Diazidesmentioning

confidence: 99%

Synthesis and Chemistry of Organic Geminal Di- and Triazides

Häring

Kirsch

2015

Molecules

View full text Add to dashboard Cite

show abstract

Section: Geminal Diazidesmentioning

confidence: 99%

Synthesis and Chemistry of Organic Geminal Di- and Triazides

Häring

Kirsch

2015

Molecules

View full text Add to dashboard Cite

show abstract

“…The syntheses of α-azidoalkyl esters by alternative methods is known in literature . But the access to these compounds is often described for single and special examples only, and the desired products are formed as mixtures with other substances in many cases .…”

mentioning

confidence: 99%

Synthesis of Geminal Azido–Halo Compounds and α-Azidoalkyl Esters from Aldehydes via α-Azido Alcohols

2017

View full text Add to dashboard Cite

show abstract

Über die Synthese von α‐Azidoestern und geminalen Triaziden

et al. 2014

View full text Add to dashboard Cite

Drei einfache Methoden zur Synthese geminaler Triazide werden beschrieben: Ausgehend von 1) 3‐Oxocarbonsäuren, 2) Iodmethylketonen oder 3) terminalen Olefinen gelingt der Aufbau einer Reihe von Triazidomethylketonen unter milden, oxidativen Reaktionsbedingungen mit IBX‐SO3K, einem sulfonierten Derivat der 2‐Iodoxybenzoesäure (IBX), und NaN3 als Azidquelle. Von dieser neuen Verbindungsklasse sind bislang keine Mitglieder beschrieben. Die geminalen Triazide erweisen sich trotz ihres hohen Stickstoffgehalts auch in präparativen Mengen als unerwartet leicht handhabbar (Vorsicht: Explosionsgefahr besteht trotzdem!) und stehen nun erstmals in voller Breite für weitere Untersuchungen zu Reaktivität und Eigenschaften zur Verfügung. Darüber hinaus zeigen wir, wie mit dieser Methode α‐Azidoester, die als Bausteine für Aminosäuren fungieren können, gebildet werden.

show abstract

Application of the nitrosoamide reaction to hydrazones

Cited by 9 publications

References 5 publications

Synthesis and Chemistry of Organic Geminal Di- and Triazides

Synthesis and Chemistry of Organic Geminal Di- and Triazides

Synthesis of Geminal Azido–Halo Compounds and α-Azidoalkyl Esters from Aldehydes via α-Azido Alcohols

Über die Synthese von α‐Azidoestern und geminalen Triaziden

Contact Info

Product

Resources

About