Application of supported metallic catalysts in catalytic hydrogenation of arenes

Qi, Shi‐Chao; Wei, Xian‐Yong; Zong, Zhi‐Min; Wang, Yin-Kai

doi:10.1039/c3ra40848e

Cited by 88 publications

(41 citation statements)

References 114 publications

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“…Therefore, new studies would be welcomed in the field of SDO catalysts. We note that relevant theoretical [136] and experimental studies [137][138][139][140][141][142][143] concerning the preparation of supported Ni catalysts are abundant in the literature but they mainly addressed to hydrogenation.…”

Section: The Effect Of Preparation Methods On the Catalytic Performancmentioning

confidence: 99%

Development of nickel based catalysts for the transformation of natural triglycerides and related compounds into green diesel: a critical review

Kordulis

Bourikas

Gousi

et al. 2016

Applied Catalysis B: Environmental

248

125

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Section: The Effect Of Preparation Methods On the Catalytic Performancmentioning

confidence: 99%

Development of nickel based catalysts for the transformation of natural triglycerides and related compounds into green diesel: a critical review

Kordulis

Bourikas

Gousi

et al. 2016

Applied Catalysis B: Environmental

248

125

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“…A large number of researches have been focused on producing high quality bio-oil, and one of the most attractive methods is catalytic fast pyrolysis (CFP) technology [2][3][4][5]. A range of zeolite catalysts has been researched in the literatures [6][7][8], and previous experimental results have confirmed that ZSM-5 zeolite performs the best to de-oxygenate pyrolysis vapors and favor hydrocarbon production [9][10][11].…”

Section: Introductionmentioning

confidence: 91%

Catalytic upgrading of fast pyrolysis biomass vapors over fresh, spent and regenerated ZSM-5 zeolites

Zhang

Zhong

Wang

et al. 2015

Fuel Processing Technology

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“…Similar-type catalysts are applied at lower temperatures for pre-reforming of propane and butane (773-873 K) [1][2][3] and as catalysts for a number of hydrogenation reactions (473-673 K) [4,5]. Working at these lower temperatures, transitional aluminas may low-temperature Rh-based catalysts in phenol steam reforming [18].…”

Section: Introductionmentioning

confidence: 99%

A study of Ni/Al2O3 and Ni–La/Al2O3 catalysts for the steam reforming of ethanol and phenol

Garbarino

Wang

Valsamakis

et al. 2015

Applied Catalysis B: Environmental

114

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a b s t r a c t samples have been prepared by conventional impregnation, using silica-free -Al 2 O 3 support. The materials have been characterized, as such or after reaction, with XRD, skeletal IR, UV-vis-NIR, XPS and FESEM techniques. The catalytic activity has been evaluated in ethanol decomposition through temperature programmed surface reaction (TPSR); and in ethanol steam reforming (ESR); and in mixed ethanol and phenol steam reforming (EPSR as a model reaction for biomass tar steam reforming) in a continuous flow reactor. Ni on alumina exists as a surface Ni x Al 2 O 3+x spinel, evident by XRD, skeletal IR and vis spectroscopy measurements. La disperses on alumina in a disordered state. In the ternary system, XPS reveals significant Ni-La interactions. The addition of some lanthanum further increases the activity of Ni/Al 2 O 3 for ESR and EPSR. Fresh unreduced catalysts are conditioned in the feed at temperatures above 973 K. Conditioned catalysts give rise to full conversion of reactants in ESR and EPSR at 873 K and higher temperatures, but are severely deactivated by sulfur. The sudden start of the steam reforming activity at 873 K likely corresponds to the temperature onset for the activation of water by metallic nickel.

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Application of supported metallic catalysts in catalytic hydrogenation of arenes

Cited by 88 publications

References 114 publications

Development of nickel based catalysts for the transformation of natural triglycerides and related compounds into green diesel: a critical review

Development of nickel based catalysts for the transformation of natural triglycerides and related compounds into green diesel: a critical review

Catalytic upgrading of fast pyrolysis biomass vapors over fresh, spent and regenerated ZSM-5 zeolites

A study of Ni/Al2O3 and Ni–La/Al2O3 catalysts for the steam reforming of ethanol and phenol

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