Application of Polymeric Membrane in CO&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt; Capture from Post Combustion

Wang, Shuangzhen; Han, Xiaochun

doi:10.4236/aces.2012.23039

Cited by 10 publications

(4 citation statements)

References 35 publications

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“…Hence, the flow through the commercial membrane materials would be significantly low in the absence of a compressing assembly for the air supply in gas separation membrane operations. These membranes also have a permeability and selectivity trade-off, which limits their general applicability, especially when high performance is required. − The ultrathin polyvinylamine (PVAm) membrane based on polysulfone was assessed, and preliminary gas separation results (selectivity ∼ 200, permeance approximately 1 m 3 STP /bar·h·m 2 ) indicate potential in the field of CO 2 capture from flue gas . These recently developed novel assisted membranes can achieve 90% purity and 90% CO 2 recovery from flue gas mixtures even at a CO 2 concentration of 10%, as shown in Figure …”

Section: Methods Of Dacmentioning

confidence: 99%

A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO₂ Concentrations and Future Perspectives

et al. 2023

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Climate change has been linked to industrial and commercial activities caused by exploitation of fossil fuels for energy needs for over a century now. A significant rise in greenhouse gas (GHG) emissions, majorly CO 2 , has been reported in the last few decades. Global climate change necessitates mitigation of atmospheric CO 2 levels to suitable margins using CO 2 capture mechanisms. Direct air capture (DAC) technology is the most efficient way to mitigate or reduce greenhouse emissions by capturing carbon dioxide directly from the atmospheric air. It is imperative that DAC technology be ramped up quickly in order to meet the climate goal to reduce global temperature rise below 2 °C in the next 30 years. This review focuses on the specifics of various techniques, pilot projects, and commercial facilities for DAC technology deployment. DAC has seen substantial technical improvement in recent years, with commercial firms already functioning in the industry with significant upmarket potential. There are about 19 DAC plants in operation across the world, absorbing around 0.01 Mt CO 2 /year. This review article discusses the various DAC technologies used by the companies, future potential, life cycle assessment, as well as the economic viability of worldwide installation of these facilities. The paper provides details on the application of various sorbents including nanomaterials for current advances in DAC. Lastly, the outlook and perspectives are also presented with the concluding remarks.

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Section: Methods Of Dacmentioning

confidence: 99%

A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO₂ Concentrations and Future Perspectives

et al. 2023

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“…Also it was shown that at gap spacing of 3 to 5 mm the removal efficiency increased to a maximum. Wang and Han reviewed CO 2 capture with polymeric Membrane [16]. According to them, hollow fiber membrane is highly gas permeable.…”

Section: An Insight Into Removal and Recovery Of So 2 And Co 2 In Petmentioning

confidence: 99%

An Insight into Removal and Recovery of SO2 and CO2 in Petroleum Industries with Emphasis on Absorption

2016

International Journal of Petroleum and Petrochemical Engineerin

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The exhaust gases from petroleum refineries contain carbon dioxide, sulphur dioxide and oxides of other compounds. Methods such as adsorption, absorption, membrane separation, chemical conversion and electrostatic separators can be used for the removal of these gases from the gaseous mixtures. The recovery of the valuable gases, which can be reused in the processes, is also important aspect of waste gas treatment. Membrane related treatment methods are effective but high cost limits their use to specific applications. Adsorption is also effective in some applications. Regeneration and solid disposal is inconvenient. Absorption is most widely used method for recovery of gases. Current review summarizes research and studies on absorption for removal and recovery of carbon dioxide and sulphur dioxide in petroleum industry waste gases.

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“…Although much work has been performed on material modification to fine-tune gas transport properties, the relationship of permselectivity to the polymer microstructure is still under investigation. Most common applications include hydrogen recovery, hydrogen separation for ammonia recovery, air separation for nitrogen production or oxygen enrichment, carbon dioxide removal from industrial processes, and removal of impurities in natural gas supplies. ,− The separation of N 2 and CO 2 from CH 4 is important in natural gas processing because N 2 and CO 2 are incombustible. However, N 2 /CH 4 separation is technically challenging because of the similar molecular size of N 2 (∼0.36 nm) and CH 4 (∼0.38 nm) .…”

Section: Introductionmentioning

confidence: 99%

Molecular Insight into 6FD Polyimide-Branched Poly(phenylene) Copolymers: Synthesis, Block Compatibility, and Gas Transport Study

Huang

Largier

Luo

et al. 2023

ACS Appl. Polym. Mater.

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A series of 6FDA-DABA (6FD) polyimide and branched poly(phenylene) (PP) block copolymers and homopolymers were successfully synthesized using Diels–Alder and polycondensation reactions. PP and 6FD homopolymer blends in tetrahydrofuran were immiscible. The result coincides with their large chemical dissimilarity and theoretical solubility parameter differences of 25.47 and 33.17 (MJ/m3)1/2. However, 6FD-PP block copolymer solutions were clear, and thin films were robust and creasable. Densities and fractional free volumes (FFV) (0.162–0.346) largely obeyed the rule of mixing, suggesting a “blend-like” morphology. At moderate PP block lengths, two distinct glass transition temperatures (340 and 420 °C) were evident, while large PP block lengths suppressed first-order polyimide transitions entirely. A small-angle X-ray scattering and atomic force microscopy morphological analysis revealed two distinct domains, with separation lengths increasing with the PP block length. Their gas permeation, diffusion, sorption, and separation properties were thoroughly investigated and exhibited a strong correlation with polymer chemistry, block length, and FFV. A block copolymer had an O2 permeability roughly between 6FD and PP, resulting in a 30% increase in O2/N2 selectivity. The N2/CH4 selectivities ranged from 4.2 to 0.58, suggesting that this 6FD-PP system could be efficiently tuned from highly N2-selective to CH4-selective performance. Five structural models, rule-of-mixture, Maxwell, equivalent box model, laminate, and blend, were used to predict gas transport properties. Compared with experimental data, the miscible blend model provided the best results for the 6FD-PP block copolymer system. Block copolymerization by combining highly selective polyimide and highly permeable branched poly(phenylene) provides an opportunity for gas separation tunability and improvement in selected gas pairs.

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Application of Polymeric Membrane in CO<sub>2</sub> Capture from Post Combustion

Cited by 10 publications

References 35 publications

A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO₂ Concentrations and Future Perspectives

A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO₂ Concentrations and Future Perspectives

An Insight into Removal and Recovery of SO2 and CO2 in Petroleum Industries with Emphasis on Absorption

Molecular Insight into 6FD Polyimide-Branched Poly(phenylene) Copolymers: Synthesis, Block Compatibility, and Gas Transport Study

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Application of Polymeric Membrane in CO&lt;sub&gt;2&lt;/sub&gt; Capture from Post Combustion

Cited by 10 publications

References 35 publications

A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO2 Concentrations and Future Perspectives

A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO2 Concentrations and Future Perspectives

An Insight into Removal and Recovery of SO2 and CO2 in Petroleum Industries with Emphasis on Absorption

Molecular Insight into 6FD Polyimide-Branched Poly(phenylene) Copolymers: Synthesis, Block Compatibility, and Gas Transport Study

Contact Info

Product

Resources

About

Application of Polymeric Membrane in CO<sub>2</sub> Capture from Post Combustion

A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO₂ Concentrations and Future Perspectives

A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO₂ Concentrations and Future Perspectives