Abstract:We attempted to realize a prototype system that monitors the living condition of indoor dogs without physical or mental burden by using a piezoelectric poly-l-lactic acid (PLLA) braided cord as a wearable sensor. First, to achieve flexibility and durability of the piezoelectric PLLA braided cord used as a sensor for indoor dogs, the process of manufacturing the piezoelectric PLLA fiber for the piezoelectric braided cord was studied in detail and improved to achieve the required performance. Piezoelectric PLLA … Show more
“…3,21,58,67 The strong frequency dependence of the piezoelectric response of PLA represents a great advantage for energy harvesting purposes, going toward high frequency in the range of kHz and MHz for remote external ultrasound activation of implantable energy harvesting devices. 68,69 Using piezoelectric PLA for slow movement, such as implantable pressure sensors 4,5 or external wearable motion tracker, 18,31 would be a less convenient application because of an expected low activation frequency of 1−2 Hz, resulting in low strain rates that may be too little to obtain an efficient piezoelectric response for reliable force sensors or motion tracking.…”
Section: Effect Of the Optical Purity On The Piezoelectricmentioning
confidence: 99%
“…Most documented piezoelectric PLA materials exhibit mainly highly oriented α and α ′ -form crystals. ,,, Densely packed α crystals are suspected to possess higher piezoelectric properties compared to α ’ crystals because the shear transmission efficiency is assumed to be higher . However, it was also reported that a degree of crystallinity and chain orientation that are too high leads to poor mechanical properties, such as low strain, low toughness, and poor tear strength, making the application of the material unfeasible. , …”
The shear piezoelectricity of polylactide (PLA) depends on the chain orientation, crystallinity, and optical purity, but their combined influence on the piezoelectric properties has never been studied. This work examines the effect of optical purity on the piezoelectric chain morphology induced by cold-drawing and heat treatment. Moreover, the influence of force and frequency during dynamic mechanical activation on the piezoelectric response of PLA was studied. The results of this work present for the first time a piezoelectric coefficient of a purely amorphous as-drawn PLA film (d 14 = 2.3 ± 0.1 pC N −1 ), exhibiting high optical purity and high chain orientation but without crystallites, leading to a ductile behavior. Postdrawn annealing increased the piezoelectric coefficient by 157% due to induced crystallinity and high crystal orientation, resulting in a brittle behavior. Upon increasing the optical purity from 88 to 99% L-isomer content, the piezoelectric coefficient (d 14 ) was shown to be improved due to the increased degree of crystallinity, chain orientation, and lamellar thickness. Dynamic mechanical analysis revealed for the first time a linear strain rate dependence of the piezoelectric response of PLA. This led to a further increase of the piezoelectric coefficient of the amorphous as-drawn film by 470% by increasing the frequency of dynamic mechanical activation to 1 kHz. These results unfold the potential for the fabrication of piezoelectric amorphous PLA films with improved ductility for final biomedical applications.
“…3,21,58,67 The strong frequency dependence of the piezoelectric response of PLA represents a great advantage for energy harvesting purposes, going toward high frequency in the range of kHz and MHz for remote external ultrasound activation of implantable energy harvesting devices. 68,69 Using piezoelectric PLA for slow movement, such as implantable pressure sensors 4,5 or external wearable motion tracker, 18,31 would be a less convenient application because of an expected low activation frequency of 1−2 Hz, resulting in low strain rates that may be too little to obtain an efficient piezoelectric response for reliable force sensors or motion tracking.…”
Section: Effect Of the Optical Purity On The Piezoelectricmentioning
confidence: 99%
“…Most documented piezoelectric PLA materials exhibit mainly highly oriented α and α ′ -form crystals. ,,, Densely packed α crystals are suspected to possess higher piezoelectric properties compared to α ’ crystals because the shear transmission efficiency is assumed to be higher . However, it was also reported that a degree of crystallinity and chain orientation that are too high leads to poor mechanical properties, such as low strain, low toughness, and poor tear strength, making the application of the material unfeasible. , …”
The shear piezoelectricity of polylactide (PLA) depends on the chain orientation, crystallinity, and optical purity, but their combined influence on the piezoelectric properties has never been studied. This work examines the effect of optical purity on the piezoelectric chain morphology induced by cold-drawing and heat treatment. Moreover, the influence of force and frequency during dynamic mechanical activation on the piezoelectric response of PLA was studied. The results of this work present for the first time a piezoelectric coefficient of a purely amorphous as-drawn PLA film (d 14 = 2.3 ± 0.1 pC N −1 ), exhibiting high optical purity and high chain orientation but without crystallites, leading to a ductile behavior. Postdrawn annealing increased the piezoelectric coefficient by 157% due to induced crystallinity and high crystal orientation, resulting in a brittle behavior. Upon increasing the optical purity from 88 to 99% L-isomer content, the piezoelectric coefficient (d 14 ) was shown to be improved due to the increased degree of crystallinity, chain orientation, and lamellar thickness. Dynamic mechanical analysis revealed for the first time a linear strain rate dependence of the piezoelectric response of PLA. This led to a further increase of the piezoelectric coefficient of the amorphous as-drawn film by 470% by increasing the frequency of dynamic mechanical activation to 1 kHz. These results unfold the potential for the fabrication of piezoelectric amorphous PLA films with improved ductility for final biomedical applications.
“…Common sense suggests that it would be difficult to detect the occurrence of bruxism with the braided PLLA piezoelectric cord sewn into the bed sheet under this condition. In previous studies, when such sensing was not possible, FEM was conducted to search for conditions under which sensing was possible [ 41 , 42 ], and a prototype sensor was successfully fabricated on the basis of FEM results. In this study, we followed the same approach and first conducted FEM to search for conditions under which the braided piezoelectric PLLA cord can be sewn into bed sheets to sense the vibration generated by bruxism.…”
“…The sewn bed-sheet-type sensor was placed on the bed and covered with a mattress pad. In this system, which is the same as the previously reported system for the signal detection circuit, the sensed signal is received by a preamplifier and then amplified 400 times by an amplifier [ 41 , 42 ]. Basic measurements were conducted to confirm the responsiveness based on the piezoelectricity of the bed-sheet-type sensor.…”
For many years, we have been developing flexible sensors made of braided piezoelectric poly-l-lactic acid (PLLA) fibers that can be tied and untied for practical applications in society. To ensure good quality of sleep, the occurrence of bruxism has been attracting attention in recent years. Currently, there is a need for a system that can easily and accurately measure the frequency of bruxism at home. Therefore, taking advantage of the braided piezoelectric PLLA cord sensor’s unique characteristic of being sewable, we aimed to provide a system that can measure the frequency of bruxism using the braided piezoelectric PLLA cord sensor simply sewn onto a bed sheet on which the subject lies down. After many tests using trial and error, the sheet sensor was completed with zigzag stitching. Twenty subjects slept overnight in a hospital room on sheets integrated with a braided piezoelectric PLLA cord. Polysomnography (PSG) was simultaneously performed on these subjects. The results showed that their bruxism could be detected with an accuracy of more than 95% compared with PSG measurements, which can only be performed in a hospital by a physician and are more burdensome for the subjects, with the subjects simply lying on the bed sheet with a braided piezoelectric PLLA cord sensor sewn into it.
“…13) Various sensing applications have been developed using piezoelectric braids. 14) Inspired by the piezoelectricity of PLA fiber, we focused on poly (3-hydroxybutyrate-co-3-hydroxyhexanote) (PHBH) fiber, which has a molecular structure like PLA. PHBH is a polymer that is biodegradable in both soil and marine environments.…”
Microscopic electromechanical response of a poly (3-hydroxybutyrate-co-3-hydroxyhexanote) (PHBH) fiber, a polymer more biodegradable than poly (lactic acid) (PLA), are observed. The crystallization of PHBH fibers is enhanced by the annealing, and a strong electromechanical response is observed in the particles. Different positive and negative electromechanical responses are observed within a single PHBH fiber particle by lateral piezoresponse force microscopy. The electromechanical response of PHBH fiber is suggested to be due to shear piezoelectricity, since the molecular chain of PHBH fiber has a helical structure similar to that of PLA and cellulose. In addition, the deformation is confirmed to be a displacement corresponding to particles of 100 ~ 300 nm in diameter.
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