2015
DOI: 10.3390/chemosensors3020190
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Application of Photocured Polymer Ion Selective Membranes for Solid-State Chemical Sensors

Abstract: Application of conducting polymers with additional functional groups for a solid contact formation and photocurable membranes as sensitive elements of solid-state chemical sensors is discussed. Problems associated with application of UV-curable polymers for sensors are analyzed. A method of sensor fabrication using copolymerized conductive layer and sensitive membrane is presented and the proof of concept is confirmed by two examples of solid-contact electrodes for Ca ions and pH.

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Cited by 6 publications
(2 citation statements)
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References 35 publications
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“…As a water layer The same trend in sensor response is seen after storing the electrode under wet conditions, only this time with significantly lower sensitivity values. More specifically, a decrease in sensitivity of 10 mV/decade was observed in all the electrodes tested, which can be attributed to the water uptake of the solid contact layer [36]. Compared to the negligible water uptake of the graphite disc electrode without solid contact (Figure S2), we see that the graphite-PVB layer is detrimental for the water uptake, which can in turn affect continuous measurements.…”
Section: Potentiometric Response Under Steady Conditions Graphite Dis...mentioning
confidence: 78%
“…As a water layer The same trend in sensor response is seen after storing the electrode under wet conditions, only this time with significantly lower sensitivity values. More specifically, a decrease in sensitivity of 10 mV/decade was observed in all the electrodes tested, which can be attributed to the water uptake of the solid contact layer [36]. Compared to the negligible water uptake of the graphite disc electrode without solid contact (Figure S2), we see that the graphite-PVB layer is detrimental for the water uptake, which can in turn affect continuous measurements.…”
Section: Potentiometric Response Under Steady Conditions Graphite Dis...mentioning
confidence: 78%
“…Most of the reported SCISEs with conductive polymers use plasticized poly(vinyl chloride) (PVC) as the ion-selective membrane (ISM) [26][27][28]. However, the PVC-based ISEs suffer from diffusion of water through the ISM and the possible formation of a water layer or water pools at the ISM/solid-contact (SC) or SC/substrate interfaces resulting in poor potential stability and weakening of the ISM adhesion to the substrate [29,30].…”
Section: Introductionmentioning
confidence: 99%