Application of oxygen-17 NMR to manganese carbonyl compounds

Kump, Robin L.; Todd, Lee J.

doi:10.1016/s0022-328x(00)86676-0

Cited by 9 publications

(1 citation statement)

References 12 publications

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“…It is our aim to initiate a programme which allows the thermal study of metal carbonyls through techniques such as TG and DSC to complement other established methods such as calorimetry [28,29], flash photolysis [30], IR [31], NM R [17][18][19] and mass spectroscopic techniques [32] which are used extensively in kinetic and mechanistic investigations. We wish to report as part of a series of thermal studies on organometallic complexes, the monosubstituted pentacarbonyl M(CO)5(dppm ) where M = Cr, Mo, and W. The dppm in these molecules functions as a monodentate ligand despite its bidentate potential.…”

mentioning

confidence: 99%

Thermal degradation of the transition metal carbonyl complexes

Chan¹,

Hor²,

Chiam³

et al. 1987

Journal of Thermal Analysis

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mentioning

confidence: 99%

Thermal degradation of the transition metal carbonyl complexes

Chan¹,

Hor²,

Chiam³

et al. 1987

Journal of Thermal Analysis

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Structural Organomanganese Chemistry

Meier¹,

Hanusa²

2011

Patai's Chemistry of Functional Groups

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In the more than 50 years since the first manganese compound with MnC bonds was crystallographically characterized (Mn 2 (CO) 10 , in 1957), the number of structurally authenticated organomanganese compounds has grown to several thousands. The richness of structural features in organomanganese compounds now rivals that of any other first row transition metal. The range of structural features and bond types is large, and encompasses MnC, MnC, and MnC bonds, as well as complexes with MnMn, MnMn, and MnMn linkages. Crystallographically characterized examples are known with oxidation states from Mn 0 to Mn V , and the accessibility of two spin states of comparable energy in complexes of Mn II adds an additional variable to the fundamental structural types. The present review of structural organomanganese chemistry focuses largely on crystallographically characterized complexes, whose geometries are the most reliably established. Representative examples of major compound classes are considered, and statistical analysis of typical bond length ranges is provided for various Mn/C and Mn/Mn interactions. Bond lengths in organomanganese compounds are highly context‐sensitive, and even when only a specific bond order is under consideration, the spread of distances makes comparisons difficult unless closely related molecules are examined.

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