Neural networks are used to solve complex problem viz., speech and image recognition, pattern recognition (Pattern classification), computer vision etc. Pattern classification by using Back Propagation algorithm for an intelligent gas sensor application is presented. The classifier is trained using published data of thick film tin oxide sensor array. Its superior classification and learning performance is demonstrated for discrimination of alcohols and alcoholic beverages by increasing number of hidden layer. The new model proposed in this article give steep and monotone learning curve and better classification efficiency. Keywords: Neural Network classifier, Back Propagation Algorithm, system error, classification efficiency, learning curve