“…i 0 between Li and PEO-based electrolytes is on the order of 1 mA/cm 2 . Interestingly, this is similar in magnitude to that reported for a typical organic electrolyte used in lithium-ion batteries, 61 but an order of magnitude lower than a liquid ether electrolyte 62 and an inorganic electrolyte. 63…”
Section: Reaction Kinetics At Solid-electrolyte-electrode Interfacessupporting
“…i 0 between Li and PEO-based electrolytes is on the order of 1 mA/cm 2 . Interestingly, this is similar in magnitude to that reported for a typical organic electrolyte used in lithium-ion batteries, 61 but an order of magnitude lower than a liquid ether electrolyte 62 and an inorganic electrolyte. 63…”
Section: Reaction Kinetics At Solid-electrolyte-electrode Interfacessupporting
“…The successful application of the microelectrode technique for the estimation of the interfacial charge-transfer rate of Li electrodes [18][19][20] is mainly based on the ability to work with very high current densities due to the negligible IR drops. When the current density that can be driven is high enough, the Li deposition process may be faster than the reaction of the Li deposits with solution species to form passivating surface films.…”
Section: Reasoning Behind the Application Of Microelectrode Techniquementioning
“…As well known, microelectrode has been used to illuminate electrochemical mechanism and obtain important electrochemical parameters of complex electrochemical reactions due to many instinct merits, such as, high mass transfer rate, low iR drop, fast response and high signal/noise (S/N) ratio [19,20]. In the present work, a micro-disc Pt electrode was used to obtain key parameters of Li + /Li electrochemical redox processes.…”
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