Application of Metal–Organic Framework and Their Derived Materials in Electrocatalysis

Gopalram, Keerthiga; Karthik, P.; Neppolian, Bernaurdshaw

doi:10.1002/9781119651079.ch13

Cited by 4 publications

(2 citation statements)

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“…MOFs represent the domain of porous coordination polymeric networks that typically contain metal ion clusters coordinated with conjugated organic ligands to form an extended net-like framework. [32] Exceptional properties of MOFs like their highly porous nature and larger surface area make them an emerging class of materials that find applications in various fields like catalysis, [33] gas separation and storage, [34] sensing, [35][36][37][38][39] biomedicine, [40,41] photocatalysis [42,43] , electrocatalysis, [44][45][46] etc. The structural adaptability, excellent porosity, and large surface area of MOFs prove beneficial for desired applications as it is feasible to tune the pore size and functionality of the MOF by employing different linker molecules.…”

Section: Introductionmentioning

confidence: 99%

Decoding the Mechanistic Strategies of Lanthanide‐based Luminescent Metal‐Organic Frameworks towards Antibiotic Detection

Yazhini,

Mathew,

Anpo

et al. 2023

Advanced Optical Materials

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Antibiotics have successfully been developed and used widely in clinical therapeutics for many years to treat bacterial infections, resulting in their unregulated discharge into waterbodies, which adversely affects the flora and fauna. This triggers alarming health issues that ascertain the need to develop suitable sensors for the detection and removal of persitent antibiotic pollutants. Several reports have been made on lanthanide‐based luminescent metal‐organic frameworks (MOFs) as one of the best‐known chemosensors that render efficient and selective detection of antibiotics owing to their intrinsic luminescent response. Herein, the recent advancements in lanthanide‐based MOFs for recognizing antibiotics are reviewed with a detailed discussion on the mechanistic routes of detection. Also, the possible transitions between the energy levels of lanthanides and the unique photophysical attributes of lanthanide‐organic hybrids are critically assessed. Further, the performance of the reported chemosensors based on their detection range, the limit of detection, stability, reproducibility, and practical feasibility are extensively explored. These unique aspects of this review provide a solid prospect for designing innovative and ingenious fluorescent probes.

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Section: Introductionmentioning

confidence: 99%

Decoding the Mechanistic Strategies of Lanthanide‐based Luminescent Metal‐Organic Frameworks towards Antibiotic Detection

Yazhini,

Mathew,

Anpo

et al. 2023

Advanced Optical Materials

Self Cite

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show abstract

“…Among several classes of electrocatalysts, metal-organic frameworks (MOFs) stand out as a new class of hybrid materials constructed from the association of inorganic building blocks connected by organic linkers, with potential properties favorable for CO 2 reduction, such as highly tunable pore size to enhance diffusion. In addition to their outstanding chemical flexibility, these properties put MOFs ahead of other well-known electrocatalysts [ [4] , [5] , [6] ]. Although there are several studies using monometallic MOFs as electrocatalysts, bimetallic organometallic frameworks outperform the catalytic activity of monometallic organometallic frameworks due to a synergistic effect [ [7] , [8] , [9] ].…”

Section: Introductionmentioning

confidence: 99%