Application of inductively coupled plasma sector field mass spectrometry for elemental analysis of urine

Rodushkin, Ilia; Ödman, Fredrik

doi:10.1016/s0946-672x(01)80010-9

Cited by 61 publications

(40 citation statements)

References 19 publications

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“…The final column in Table 4 23 In addition, the Sb and Ba urine concentrations of the present study were significantly lower than those for a UK population investigated in 1992. for quantification of ultra-trace elements. In comparing the present results with more recent studies performed on European groups, the present data overlapped those of the Swedish 22 and German 21 population for Ba as well as for Sb, while Cs and W were not comparable-both being much lower than those published. Finally, our data compared favorably with those obtained in the USA population for Ba and Cs, while they were visibly lower for Sb and W. 19,20 In particular, the USA concentrations of Sb and W were up to 20-fold higher than ours and closer to the data presented by Minoia et al 23 The occurrence of all these discrepancies found could testify to the need for the development of more powerful techniques and for improved attention to be paid to contamination problems during the analysis as well as to the inherent characteristics of the different populations studied.…”

supporting

confidence: 69%

Uncertainty of inductively coupled plasma mass spectrometry based measurements: an application to the analysis of urinary barium, cesium, antimony and tungsten

Alimonti¹,

Forte²,

Spezia

et al. 2005

Rapid Comm Mass Spectrometry

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The wide use of barium (Ba), cesium (Cs), antimony (Sb) and tungsten (W) in many industrial and agricultural fields causes the increased release of these metals into the environment, laying the basis for health risk. To assess the exposure for the general population, the development of adequate and reliable analytical techniques becomes compulsory. This study refers to the quantification of urinary Ba, Cs, Sb and W levels by both quadrupole (Q) and sector field (SF) inductively coupled plasma mass spectrometry (ICP-MS). The two procedures were compared for their performances and their measurement uncertainties. The limits of detection were (Q and SF) 23.0 and 5.21 ng L(-1) for Ba; 21.1 and 7.52 ng L(-1) for Cs; 1.09 and 0.43 ng L(-1) for Sb; and 0.36 and 0.49 ng L(-1) for W. The trueness was better than 93.3% and the precision less than 12% for both techniques. Relative expanded uncertainties of the analytical procedures, at the median levels found in the general population, were below 5% for all the elements with both ICP-MS techniques. The uncertainties related to the calibration and repeatability were the parameters most influencing the final analytical performance. The urinary median values observed in healthy subjects from central Italy were 1146, 4301, 60.8 and 48.5 ng L(-1) for Ba, Cs, Sb and W, respectively.

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supporting

confidence: 69%

Uncertainty of inductively coupled plasma mass spectrometry based measurements: an application to the analysis of urinary barium, cesium, antimony and tungsten

Alimonti¹,

Forte²,

Spezia

et al. 2005

Rapid Comm Mass Spectrometry

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“…In is used for the intermediate masses and 185 Re for the higher ones (from 150 to 240 amu) [36][37][38][39] . The choice of the internal standards for the present study was also based in the preliminary results obtained for the accuracy and recuperation parameters.…”

mentioning

confidence: 99%

Multi-Element Analysis of Some Toxic Metals in Urine using Quadrupole ICP-MS

Soubhia¹,

Capitani²,

Buzzo

et al. 2017

Asian Journal of Chemistry and Pharmaceutical Sciences

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Occupational and environmental metal contamination is a global concern due to the occurrence of long term health effects in many organ systems. Deficiency or excess of essential metals, depending on personal and/or population nutritional status are also a big public health concern, requiring regular evaluation for early diagnosis and eventual therapeutic intervention. The objective of this study was to validate an easy and rapid analytical method using ICP-MS for the determination of 17 metals (As, Sb -semimetals; Be, Cd, Li, Pb, Pd, Pt, Rh, Sr, Tl, Mn -metals; Mo, Ni, Cr, Cu, Se -essential metals 1 ) of toxicological interest. The studied working range demonstrated evidence of linearity and the proposed method proved to be accurate, with good repeatability and intermediate precision. Obtained Limit of Detection (LOD) for the studied analytes were lower or equal to those obtained by CDC in urine.

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“…15,16 The complex matrices, most often rich in carbon and salts, require devices to cope with spectral interferences at steadily decreasing concentration levels. [17][18][19][20] A review by Krachler highlights the factors that make ICP-SFMS a very powerful tool in environmental analysis. 15 These include the extremely low detection limits, tremendously high sensitivity, the ability to separate analyte signals from spectral interferences and an attractive precision for isotope ratio measurements even at low elemental concentrations and for large isotope ratios (i.e.…”

Section: Biological and Environmental Samplesmentioning

confidence: 99%

Inductively coupled plasma- and glow discharge plasma-sector field mass spectrometry : Part II. Applications

Jakubowski

Prohaska

Vanhaecke

et al. 2011

J. Anal. At. Spectrom.

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Application of inductively coupled plasma sector field mass spectrometry for elemental analysis of urine

Cited by 61 publications

References 19 publications

Uncertainty of inductively coupled plasma mass spectrometry based measurements: an application to the analysis of urinary barium, cesium, antimony and tungsten

Uncertainty of inductively coupled plasma mass spectrometry based measurements: an application to the analysis of urinary barium, cesium, antimony and tungsten

Multi-Element Analysis of Some Toxic Metals in Urine using Quadrupole ICP-MS

Inductively coupled plasma- and glow discharge plasma-sector field mass spectrometry : Part II. Applications

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