Application of GATES and MATLAB for Resolution of Equilibrium, Metastable and Non-Equilibrium Electrolytic Systems

Principles of Titrimetric Analyses According to Generalized Approach to Electrolytic Systems (GATES)

“…[21]. Other examples of high degree of complexity are shown in the works [9,11,12,[14][15][16]. One of the examples in Ref.…”

“…In Figure 2, the monotonic drops of E ¼ E(Φ), i.e., dE/dΦ < 0, are accompanied by nonmonotonic changes of pH ¼ pH(Φ) [9,46,47].…”

“…[7,9,[46][47][48][49]. The nonmonotonic pH versus V relationships were also stated in experimental pH titrations made in some binary-solvent media [33].…”

“…The detailed considerations in this chapter are based on principles of the generalized approach to electrolytic systems (GATES), formulated by Michałowski [9] and presented recently in a series of papers, related to redox [7][8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23][24][25][26] and nonredox systems [27][28][29][30][31][32] in aqueous and in mixed-solvent media [33][34][35][36][37]. The closed system separated from its environment by diathermal walls secure a heat exchange between the system and its environment, and realize dynamic processes in a quasistatic manner under isothermal conditions.…”

“…Nonredox systems are formulated with use of charge (ChB) and concentration balances f(Y g ), for elements/cores Y g 6 ¼ H, O. The description of redox systems is complemented by generalized electron balance (GEB) concept, discovered by Michałowski as the Approach I to GEB (1992) and the Approach II to GEB (2006); GEB is considered as a law of a matter conservation, as the law of nature [7,9,11,13,25].…”