2016
DOI: 10.1007/s11783-016-0843-0
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Application of electrochemical depassivation in PRB systems to recovery Fe0 reactivity

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Cited by 11 publications
(3 citation statements)
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“…Since at low pH the adsorbent surface remains protonated, hence the anionic Cr species are adsorbed on the surface through electrostatic interaction [ 37 ]. It has been shown that in an aqueous medium, Cr may exist in different ionic forms such as chromate (CrO 4 −2 ), dichromate (Cr 2 O 7 − ), and hydrogen chromate (HCrO 4 − ), which primarily depend upon the pH of the medium [ 38 ]. Generally, under acidic medium, the predominant oxy anionic Cr species are HCrO 4 − and Cr 2 O 7 −2 ions, whereas under basic medium, the CrO 4 −2 is more stable [ 39 ].…”
Section: Resultsmentioning
confidence: 99%
“…Since at low pH the adsorbent surface remains protonated, hence the anionic Cr species are adsorbed on the surface through electrostatic interaction [ 37 ]. It has been shown that in an aqueous medium, Cr may exist in different ionic forms such as chromate (CrO 4 −2 ), dichromate (Cr 2 O 7 − ), and hydrogen chromate (HCrO 4 − ), which primarily depend upon the pH of the medium [ 38 ]. Generally, under acidic medium, the predominant oxy anionic Cr species are HCrO 4 − and Cr 2 O 7 −2 ions, whereas under basic medium, the CrO 4 −2 is more stable [ 39 ].…”
Section: Resultsmentioning
confidence: 99%
“…Some simple tests have been presented (Reardon 1995(Reardon , 2005Noubactep et al 2009a;Noubactep 2011aNoubactep , 2012bLi et al 2016) whose adoption would accelerate the understanding of Fe 0 /H 2 O systems. However, properly modeling the behavior of Fe 0 filters goes exclusively through the characterization of the long-term kinetics of relevant particles and field conditions (Lu et al 2016;Sun et al 2016). 2+ species are reported to form hydrous ferric oxide (HFO) upon oxidation and As adsorbed on HFO is efficiently removed by a (subsequent) sand filtration (Gottinger et al 2013;Kowalski and Søgaard, 2014;Wan et al 2016).…”
Section: Designing Fe 0 Filters From Laboratory Datamentioning
confidence: 99%
“…In this context, Fe 0 is currently regarded as (1) a reductant for some species, (2) an adsorbent for other species, (3) a coagulant for various anionic species (Richardson and Nicklow 2002;Noubactep 2010a;Shrimpton et al 2015;Lu et al 2016;Sun et al 2016;Xu et al 2016) and (4) a long-term supplier of Fe 2+ for activation of oxidation processes (Liang and Guo 2010;Segura et al 2015;Lee et al 2014;Lin et al 2016). The properties making Fe 0 suitable for environmental remediation include: (1) its readily availability and (2) its environmental friendliness implying the generation of non-toxic hydroxides and oxides.…”
Section: Introductionmentioning
confidence: 99%