The phenomenon of
spontaneous combustion of “oxidized coal”
is common in mining processes of goafs, thick coal seams, and unsealing
of closed fire areas. In order to study the reburning characteristics
of coal with different oxidation degrees, the oxygen concentration
in the pre-oxidation process was selected as the key influencing factor.
Thermogravimetric analysis (TGA) and in situ Fourier-transform infrared
(FT-IR) spectroscopy were used to study the macro- and microcharacteristics
of raw and oxidized coal during the combustion stage. The results
showed that the pre-oxidation treatment exhibited a dual effect on
promoting and inhibiting the weight loss characteristics of oxidized
coal. The apparent activation energy, E
a, of the combustion reaction for the utilized coal samples was calculated
using the Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunose
(KAS) methods, and it was found that the average apparent activation
energy (E
a̅) values of the oxidized
coal samples were less in magnitude than that of the raw coal and
that the coal sample with the pre-oxidized oxygen concentration of
15% was more prone to the combustion reaction. Using the correlation
determination method of key active groups in the proposed coal combustion
reaction, the key active groups affecting the weight change of the
tested coal samples during the combustion stage were determined as
−CH3 and C–O. The results can be helpful
to prevent and control coal spontaneous combustion during re-mining
and unsealing of closed fire areas.