Application of a cold plasma process for polymerization and copolymerization of fluorinated and hydrogenated (meth)acrylates

Hochart, Fabienne; Levalois-Mitjaville, Joëlle; Jaeger, Roger De

doi:10.1016/s0032-3861(99)00496-6

Cited by 13 publications

(9 citation statements)

References 12 publications

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“…), ozone gener-ation [7][8][9][10][11][12] , air and water depollution (including volative organic compounds removal) 9,[13][14][15][16] or plasma-assisted combustion 17 . Meanwhile, plasmachemical synthesis has barely ventured beyond (nano-)material synthesis [18][19][20][21][22][23][24] , plasma-assisted polymerization [25][26][27] and a couple of gas-phase reactions (including benzene hydroxylation [28][29][30][31][32] and methane reforming [33][34][35][36][37] ).…”

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confidence: 99%

Microfluidic chips for plasma flow chemistry: application to controlled oxidative processes

et al. 2018

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Section: Introductionmentioning

confidence: 99%

Microfluidic chips for plasma flow chemistry: application to controlled oxidative processes

et al. 2018

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“…[1][2][3][4][5] The application of fluorinated polymers has been limited due to their high price; currently, they are mainly used in aerospace and military fields. 5 Increasing attention has been paid to the incorporation of fluorinated groups and other moieties into synthetic materials since the pioneering works by Percec and coauthors in 1991, [6][7][8][9] which combine the advantages of both fluorinated groups and other polymers. [6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21][22] In addition, Percec and coauthors also demonstrated the role of fluorinated molecules and of the fluorous phase on different areas of chemistry.…”

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confidence: 99%

Synthesis, surface property, micellization and pH responsivity of fluorinated gradient copolymers

Chen

Luo

2012

J. Polym. Sci. A Polym. Chem.

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In this work, fluorinated nonamphiphilic gradient copolymers of tert-butyl acrylate (tBA) and 2,2,3,3,4,4,4-heptafluorobutyl methacrylate (HFBMA) [poly(tBA-grad-HFBMA)] were first synthesized by semibatch atom transfer radical copolymerization of tBA and HFBMA. Their hydrolysis at acidic conditions led to amphiphilic poly(acrylic acid-grad-HFBMA). The chemical compositions and structures of these copolymers were characterized by proton nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, and gel permeation chromatography. Their surface properties were evaluated with water contact angle measurement and x-ray photoelectron spectroscopy. The micellization behaviors of amphiphilic copolymer were also studied by transmission electron microscopy and dynamic light scattering. The results showed that the fluorinated and amphiphilic gradient copolymers could self-assemble in a dilute solution to form aggregates of morphologies. Furthermore, the effect of pH on the aggregates was investigated to verify that the resulting gradient copolymers were to some extent pH sensitive.

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“…[1][2][3][4] These give rise to excellent properties, such as low surface tension, good water repellence, weather resistance, low glass transition temperature, and thermal stability. Work on modifying polyacrylics and poly(acrylic-co-styrene) has been done by many researchers.…”

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Preparation and properties of room temperature self‐crosslinking poly(MMA‐co‐BA‐co‐St‐co‐VTES) latex film

et al. 2005

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Self-crosslinking poly(methyl methacrylate-co-n-butyl acrylate-co-styrene-co-vinyltriethoxysilane) latex particles were prepared by seed emulsion polymerization. The presence of Si O Si in the prepared copolymer latex particle was confirmed by FT-IR. The crosslinking degree of the polymer latex particle was investigated by using tetrahydrofuran to swell the dried copolymer films with different vinyltriethoxysilane contents. The thermal properties of the solid films were investigated by using DSC and TGA. In addition, the mechanical properties and water resistances of the different copolymer films were also investigated in detail. It was found that the mechanical properties of the copolymer film could be enhanced by introducing vinyltriethoxysilane, and the water resistance of the copolymer film could be improved at certain vinyltriethoxysilane contents. C 2005 Wiley Periodicals, Inc.

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Application of a cold plasma process for polymerization and copolymerization of fluorinated and hydrogenated (meth)acrylates

Cited by 13 publications

References 12 publications

Microfluidic chips for plasma flow chemistry: application to controlled oxidative processes

Microfluidic chips for plasma flow chemistry: application to controlled oxidative processes

Synthesis, surface property, micellization and pH responsivity of fluorinated gradient copolymers

Preparation and properties of room temperature self‐crosslinking poly(MMA‐co‐BA‐co‐St‐co‐VTES) latex film

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