Abstract:In this paper, we demonstrated the feasibility of the Aerosol Deposition (AD) method which can be adapted as a future fabrication process for flexible electronic devices. On the basis of this method’s noticeable advantages such as room-temperature processing, suitability for mass production, wide material selectivity, and direct fabrication on a flexible substrate, we fabricated and evaluated a flexible conductive bridge random access memory (CBRAM) to confirm the feasibility of this method. The CBRAM was fabr… Show more
“…Due to the thickness limitation, conventional mechanical testing methods on a macroscopic scale, for example, flexural bending tests, are not applicable to AD films. In this regard, indentation tests, including nanoindentation and Vickers indentation, are more favorable for the investigation of mechanical properties of AD films 29,30 . In the specific case of AD‐BT films, nanoindentation has been performed by Kim et al 29 .…”
Section: Introductionmentioning
confidence: 99%
“…In this regard, indentation tests, including nanoindentation and Vickers indentation, are more favorable for the investigation of mechanical properties of AD films. 29,30 In the specific case of AD-BT films, nanoindentation has been performed by Kim et al 29 to correlate surface morphologies and dielectric properties to film hardness as well as finding the boundary of minimum film thickness with AD-BT films in terms of acceptable leakage current. However, only the as-processed state has been covered in the previous study, leaving open questions regarding the mechanical properties of the film following thermal treatment.…”
Aerosol deposition (AD) is a room‐temperature film deposition method for the fabrication of scalable ferroelectric ceramic films on different substrates, which is particularly appealing for thick film energy storage applications. However, the electrical and mechanical properties of AD ferroelectric films are not yet satisfactorily understood. Here, we report the dielectric, energy storage, and mechanical properties of aerosol‐deposited BaTiO3 (AD‐BT) thick films with nanosized grains by combining macroscopic electric measurements with indentation tests. We find that thermal annealing is an effective way to improve dielectric permittivity and polarization of the AD‐BT film, as well as to increase the hardness and Young's modulus of the film. However, crack formation in the annealed AD‐BT film is promoted in comparison to the as‐processed sample, suggesting that the interplay between the nanosized grains and release of the internal stress during annealing may have major consequences for the mechanical properties and hence should be taken into consideration in application.
“…Due to the thickness limitation, conventional mechanical testing methods on a macroscopic scale, for example, flexural bending tests, are not applicable to AD films. In this regard, indentation tests, including nanoindentation and Vickers indentation, are more favorable for the investigation of mechanical properties of AD films 29,30 . In the specific case of AD‐BT films, nanoindentation has been performed by Kim et al 29 .…”
Section: Introductionmentioning
confidence: 99%
“…In this regard, indentation tests, including nanoindentation and Vickers indentation, are more favorable for the investigation of mechanical properties of AD films. 29,30 In the specific case of AD-BT films, nanoindentation has been performed by Kim et al 29 to correlate surface morphologies and dielectric properties to film hardness as well as finding the boundary of minimum film thickness with AD-BT films in terms of acceptable leakage current. However, only the as-processed state has been covered in the previous study, leaving open questions regarding the mechanical properties of the film following thermal treatment.…”
Aerosol deposition (AD) is a room‐temperature film deposition method for the fabrication of scalable ferroelectric ceramic films on different substrates, which is particularly appealing for thick film energy storage applications. However, the electrical and mechanical properties of AD ferroelectric films are not yet satisfactorily understood. Here, we report the dielectric, energy storage, and mechanical properties of aerosol‐deposited BaTiO3 (AD‐BT) thick films with nanosized grains by combining macroscopic electric measurements with indentation tests. We find that thermal annealing is an effective way to improve dielectric permittivity and polarization of the AD‐BT film, as well as to increase the hardness and Young's modulus of the film. However, crack formation in the annealed AD‐BT film is promoted in comparison to the as‐processed sample, suggesting that the interplay between the nanosized grains and release of the internal stress during annealing may have major consequences for the mechanical properties and hence should be taken into consideration in application.
“…This suggests that that the SAY particle broke with the partially damaged substrate immediately after impact. Subsequently, broken SAY particles were anchored in the glass substrate due to the generated thermal energy [13]. The interface of STS304 was observed as a film surrounding the substrate surface (Figure 4(c)), unlike the case of the Al 2 O 3 and glass substrates.…”
Section: Resultsmentioning
confidence: 99%
“…Previous studies reported that when particles accelerated by a carrier gas collide with the substrate, the kinetic energy is converted to impact energy [8,11,12]. At this time, the particles are crushed by the impact energy, which instantaneously generates thermal energy at the contact point of the crushed particles, anchoring them to the substrate [13,14]. Therefore, the initial coating layer state is affected by the hardness of the substrate.…”
Films fabricated by aerosol deposition (AD) can be coated through interactions between the particles and substrate. Accelerated particles collide with the substrate, generating impact energy at the contact point. These interactions depend on the hardness of the substrate. This study examined the effects of the hardness of the substrate on the deposition behavior of thick glass films by AD. Substrates with different hardness, Al 2 O 3 , glass, and STS304, were used, and the film formation behavior was observed. The coating thickness of the initial layer was inversely proportional to the hardness of the substrate. The STS304 substrate exhibited a phase transition after the coating process that was induced by the strong impact energy. The film formation mechanism depending on the substrate hardness was proposed based on the microstructure of the interface between the film and substrate.
“…The sensor is fabricated by a one-step aerosol deposition (AD) process, which has numerous advantages, such as fast coating speed, film deposition at low vacuum, full-room-temperature process without any heat treatment, and rigid film-to-substrate adhesion [37][38][39]. The AD process has considerable advantages over conventional technologies because a composite film can be easily prepared by simply mixing and loading more than two materials [40][41][42]. The AD principle is defined by the hammering effect, wherein high-speed particles continuously collide with pre-deposited layers; consequently, the internal density is dominated by the layer thickness and mechanical properties of each material [43,44].…”
A highly polarizable moisture sensor with multimodal sensing capabilities has great advantages for healthcare applications such as human respiration monitoring. We introduce an ionically polarizable moisture sensor based on NaCl/BaTiO3 composite films fabricated using a facile aerosol deposition (AD) process. The proposed sensing model operates based on an enormous NaCl ionization effect in addition to natural moisture polarization, whereas all previous sensors are based only on the latter. We obtained an optimal sensing performance in a 0.5 µm-thick layer containing NaCl-37.5 wt% by manipulating the sensing layer thickness and weight fraction of NaCl. The NaCl/BaTiO3 sensing layer exhibits outstanding sensitivity over a wide humidity range and a fast response/recovery time of 2/2 s; these results were obtained by performing the one-step AD process at room temperature without using any auxiliary methods. Further, we present a human respiration monitoring system using a sensing device that provides favorable and stable electrical signals under diverse respiratory scenarios.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.