Applicability and mathematical verification of the reactivity–selectivity principle in the oxidation of thioanisoles by oxo(salen)manganese(V) complexes

Mechanism of oxidation of aryl methyl sulfoxides with sodium hypochlorite catalyzed by (salen)MnIII complexes

“…As the isolation of pure oxo(salen)manganese(V) complexes is difficult [7][8][9][10]15,18], they were generated in situ for the studies reported here.…”

“…We have initiated a systematic study on the oxygenation reactions of the organic sulfides and sulfoxides with oxometal complexes by taking Cr, Mn and Ru as metal ions. We have reported the mechanism of oxidation of organic sulfides [7][8][9] and sulfoxides [10] with PhIO catalyzed by (salen)Mn III complexes and also the successful application of the reactivity-selectivity principle (RSP) to these oxidation reactions. The mechanistic studies of (1)…”

Oxidation of methionines by oxochromium(V) cations: A kinetic and spectral study

“…On the other hand such l-oxo dimer's are found to be an alternate source of oxygen in oxo(salen)manganses complexes [69].…”

Oxidation of benzaldehyde in films by Oxo-Cr(V) salen derivatives at solid/liquid interface

“…Metal oxo complexes have been invoked as models of intermediates in enzymatic oxidation cycles of cytochrome [29] and most of the chromium compounds [30] are oxo derivatives featuring a O=Cr V unit [31,32]. Reactions of such species with twoelectron reductants such as sulfides, sulfites, nitrites, and olefins may proceed by direct transfer of oxo-oxygen from oxochromium(V) species [33][34][35]. A number of studies on the redox chemistry of chromium(V) and the mechanism of oxygenation of inorganic nitrite [24] and vanadium(IV) [36] by oxochromium(V) salen complex, where salen = N ,Nethylenebis (salicylideneimine) in acetonitrile medium, have recently been reported by us.…”