Detailed neutron diffraction measurements on a single crystalline TbB 2 C 2 in which magnetic field induced antiferroquadrupolar orderings are realised have been performed to understand characteristics of the transition under zero magnetic field. The results indicate that the magnetic transition phenomena consist of development of at least three magnetic components: (1) a dominant antiferromagnetic component which develops below T N ¼ 21:7 K, (2) a weak long periodic component which develops below about 18 K, and (3) anomalous components with broad magnetic scatterings which develop below about 50 K, which can not be understood by only a short range magnetic ordering. Since these three components develop independently, the transition phenomena in TbB 2 C 2 are much more complicated than expected from a typical -type anomaly at T N in the temperature dependence of magnetic specific heat.