Three-dimensional nanocrystalline Ag–C composites
containing
a hexagonal diamond structure were produced by electrochemical reduction
of acetic acid and electrodeposition of Ag(NO3) (0.01 M)
at −1.1 V vs Ag/AgCl at ambient conditions. After applying
the negative potential, an ultrathin layer of Ag (<0.1 μm)
was first deposited, and subsequently, competitive electrodeposition
of Ag and electroreduction of acetic acid resulted in the formation
of nanocrystalline Ag–C products on the electrodes. A combination
of microscopic, structural, and spectroscopic characterization results
reveals that the nanocrystalline Ag–C contains a hexagonal
diamond structure with an average crystallite size of 26 nm. The nanodiamond
phase remained unchanged throughout 15–140 min reaction time.
However, increasing the reaction time, the thickness of nanocrystalline
Ag–C films increased to ∼2 μm with some large
polyhedra carbon structures. The nanocrystalline Ag–C composites
were utilized in the casting process of sterling silver to enhance
its antitarnish properties. The antitarnishing of sterling silver
upon exposure to a H2S environment was significantly improved
by 50% with 0.005 wt % loading of the Ag–C composite.