Ionic
salts as anti-icing agents have been extensively used to
eliminate accumulation of ice on asphalt surfaces. However, salt can
be easily removed by rain or automobiles and requires frequent application
on roads. Besides this economic consideration, anti-icing agents compromise
the mechanical properties of asphalt and have a negative impact on
living organisms and the environment when used in large amounts. Incorporation
of hydrophilic salts into bitumen, a hydrophobic asphalt binder, and
controlled release of specific molecules from this hydrophobic medium
can provide an effective solution for reducing ice formation on pavements.
Bitumen has previously been modified by various polymers, including
styrene-butadiene-styrene (SBS) for improved strength and thermomechanical
properties. However, an anti-icing function was not considered in
those previous designs. In a previous study, we developed a functional
polymer composite consisting of potassium formate (HCOOK) salt pockets
dissolved in a hydrophilic gel medium and dispersed in a hydrophobic
SBS polymer matrix. Here, we developed an innovative method to obtain
polymer composite-modified bitumen and investigated further the anti-icing
properties of the functional bitumen. We improved incorporation of
this polymer composite into bitumen and demonstrated proper distribution
of the composite within bitumen through morphological and rheological
analysis. We characterized the anti-icing properties of modified bitumen
surfaces and demonstrated significant increases in freezing delay
of composite-modified bitumen compared to base bitumen in a temperature-
and humidity-controlled chamber. In addition, we characterized the
release of HCOOK salt from polymer composite-modified bitumen and
observed salt release within the range of 1.07–10.8% (w/w)
in 67 days, depending on the composite content. The results demonstrate
the potential of this polymer composite-modified bitumen for anti-icing
functionality and for industrially relevant applications.