“…Among the various members of the magnetic equiatomic family (general formula MM X , where M and M are transition metals and X is a nonmagnetic sp element), MnNiGe is widely accepted as a promising candidate for practical applications as it possess multiple functional properties, including the shape memory effect, a large magnetocaloric effect, magnetoresistance, the exchange bias effect, etc. [8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23]. In addition, the undoped MnNiGe alloy undergoes multiple phase transformations (structural and magnetic depending on the thermal state of the material), namely, (i) MPT around 470 K from the high-temperature Ni 2 In-type hexagonal austenite phase (space group P6 3 /mmc) to the TiNiSi-type orthorhombic martensite phase (space group Pnma) and (ii) a paramagnetic (PM) to spiral antiferromagnetic (AFM) transition below or around 346 K [8][9][10]16,[24][25][26][27][28].…”