“…Since its appearance and until now, nanoscale ferroics (ferromagnets, ferroelectrics, ferroelastics) have been the main object of fundamental research on the physical nature of long-range order of polar, magnetic, and structural properties [1][2][3]. The leading role is played by the emergence of a domain structure of long-range order parameters, such as electric polarization, magnetization, and (anti)ferrodistortion, and its interaction with the surface of nanoferroic [4,5]. In nanoferroics, the role of the surface increases significantly with a decrease in their size and very often begins to dominate in comparison with the bulk contribution [6].…”