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The sections in this article are Introduction General Feature of Electroorganic Synthesis Specificity and Prospects Choice of a Cell Choice of Electrode Material Materials for Cathodes Materials for Anodes Main Reactions Achievable Electrochemically: A Survey of Experimental Conditions Some Specific Electrochemical Reactions Involving Carbon Atoms Building of CarbonCarbon Bonds at the Anode and the Cathode Kolbe Reaction: Anodic Oxidation of Carboxylates: Coupling of Aliphatic Free Radicals Anodic Oxidation of Carbanions and Symmetrical Coupling Anodic Oxidation of Aromatic Systems via Cation Radicals (Dimerizations, Trimerizations, Oligo, and Polymerizations) Cathodic Coupling of Aryl Groups via Transition Metals Catalysis Other Activation Reactions Involving Aromatic Halides in the Presence of Metal Catalysts Aromatic Carboxylations Electrosynthesis as a Tool to Afford Cyclizations Anodic Substitution of Organic Derivatives Possessing a Mobile Hydrogen Functionalizations of Nitrogen‐containing Compounds Oxidation of C H Functions Anodic Functionalization of Ethers Anodic Oxidation of Thioethers Electrochemical Conversion of Main Organic Functions in Aqueous and Protic Organic Media Reduction of Unsaturated Compounds Nitro Group Reduction of Functions Possessing at Least One Nitrogen Atom Reduction of the Carbonyl Group Organic Acids and Derivatives Scission of Chemical Bonds by Means of Cathodic or Anodic Electron Transfers Main Cathodic Scission Reactions of CarbonHeteroatom Bonds Other Types of Bond Scissions Application of the Electrochemical Scission of Bonds to the Chemical Deprotection Anodic Deprotection of the Carbonyl Group: Cleavage of C S Bonds Amine Function Deprotection: Cathodic Cleavages of C S and N S Bonds Protection and Deprotection of Alcohols and Thiols Electrosynthesis as a Tool for a New Solid‐Phase Methodology What is the State of the Art for Organic Silicon Derivatives? Electroreduction Electrooxidation Some Words about the Use of Selenium in Organic Synthesis Electroreduction Electrooxidation Electrochemical Activation of Small Inorganic Molecules Usable in Organic Synthesis Cathodic Intermediates from Dioxygen and Principal Types of Reactions Reduction of Carbon Dioxide Cathodic Behavior of Sulfur, Tellurium, and Selenium: an Easy Way of Forming Specifically Reactive Nucleophiles Anodic Activation of Molecular Sulfur and of S S Bonds Oxidation of Halides Anodic Fluorination Zero‐current Electrolyses Elements of Electrochemical Chiral Synthesis Some Models of Electrolysis Cells: From Laboratory Cells to Scaling up Laboratory Cells Industrial Cells Possible Industrial Applications of Organic Electrosynthesis
The sections in this article are Introduction General Feature of Electroorganic Synthesis Specificity and Prospects Choice of a Cell Choice of Electrode Material Materials for Cathodes Materials for Anodes Main Reactions Achievable Electrochemically: A Survey of Experimental Conditions Some Specific Electrochemical Reactions Involving Carbon Atoms Building of CarbonCarbon Bonds at the Anode and the Cathode Kolbe Reaction: Anodic Oxidation of Carboxylates: Coupling of Aliphatic Free Radicals Anodic Oxidation of Carbanions and Symmetrical Coupling Anodic Oxidation of Aromatic Systems via Cation Radicals (Dimerizations, Trimerizations, Oligo, and Polymerizations) Cathodic Coupling of Aryl Groups via Transition Metals Catalysis Other Activation Reactions Involving Aromatic Halides in the Presence of Metal Catalysts Aromatic Carboxylations Electrosynthesis as a Tool to Afford Cyclizations Anodic Substitution of Organic Derivatives Possessing a Mobile Hydrogen Functionalizations of Nitrogen‐containing Compounds Oxidation of C H Functions Anodic Functionalization of Ethers Anodic Oxidation of Thioethers Electrochemical Conversion of Main Organic Functions in Aqueous and Protic Organic Media Reduction of Unsaturated Compounds Nitro Group Reduction of Functions Possessing at Least One Nitrogen Atom Reduction of the Carbonyl Group Organic Acids and Derivatives Scission of Chemical Bonds by Means of Cathodic or Anodic Electron Transfers Main Cathodic Scission Reactions of CarbonHeteroatom Bonds Other Types of Bond Scissions Application of the Electrochemical Scission of Bonds to the Chemical Deprotection Anodic Deprotection of the Carbonyl Group: Cleavage of C S Bonds Amine Function Deprotection: Cathodic Cleavages of C S and N S Bonds Protection and Deprotection of Alcohols and Thiols Electrosynthesis as a Tool for a New Solid‐Phase Methodology What is the State of the Art for Organic Silicon Derivatives? Electroreduction Electrooxidation Some Words about the Use of Selenium in Organic Synthesis Electroreduction Electrooxidation Electrochemical Activation of Small Inorganic Molecules Usable in Organic Synthesis Cathodic Intermediates from Dioxygen and Principal Types of Reactions Reduction of Carbon Dioxide Cathodic Behavior of Sulfur, Tellurium, and Selenium: an Easy Way of Forming Specifically Reactive Nucleophiles Anodic Activation of Molecular Sulfur and of S S Bonds Oxidation of Halides Anodic Fluorination Zero‐current Electrolyses Elements of Electrochemical Chiral Synthesis Some Models of Electrolysis Cells: From Laboratory Cells to Scaling up Laboratory Cells Industrial Cells Possible Industrial Applications of Organic Electrosynthesis
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