2006
DOI: 10.1179/174328006x102501
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Anodic bonding

Abstract: Originally developed in the late 1960s, anodic bonding, also known as electrostatic bonding, field-assisted bonding or Mallory bonding, has become one of the most important silicon packaging techniques. Despite its industrial relevance the bonding mechanism is mainly only qualitatively understood and is almost solely applied to the bonding of silicon to Pyrex glass. The objective of the present paper is to review the current state of knowledge of the anodic bonding process. Possible material combinations and c… Show more

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Cited by 116 publications
(73 citation statements)
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References 183 publications
(452 reference statements)
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“…The phenomenon is known as anodic adhesion and was recently reviewed by Knowles and van Helvoort. 17 The changes in the infrared spectra ͑Fig. 4͒ of the anodic surface are much more pronounced than that of the cathodic one, indicating that the glass structure near the anode has been highly modified.…”
Section: Discussionmentioning
confidence: 98%
“…The phenomenon is known as anodic adhesion and was recently reviewed by Knowles and van Helvoort. 17 The changes in the infrared spectra ͑Fig. 4͒ of the anodic surface are much more pronounced than that of the cathodic one, indicating that the glass structure near the anode has been highly modified.…”
Section: Discussionmentioning
confidence: 98%
“…We aim to seal glass to silicon and therefore must match CTEs to reduce stresses and therefore increase yield. Pyrex is the most common glass bonded to silicon due to their comparable CTEs and its sodium content required for anodic bonding 136 (see Section IV C). This borosilicate glass is so highly permeable to helium that we should expect to lose UHV several days after bonding (see Figure 4).…”
Section: B Permeationmentioning
confidence: 99%
“…Should anodic bonding be used to seal the chips, oxygen will be released along the inner bonding edges where the voltage is high and no silicon exists to bond with the non-bridging oxygen atoms 136,172,241 . Predicting the amount of oxygen released is unreliable due to the lack of data and the effects of bonding parameters, chip dimensions, and increased outgassing at raised temperatures.…”
Section: Other Gasesmentioning
confidence: 99%
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“…2 The process is particularly useful for microelectromechanical system ͑MEMS͒ pressure sensors and other transducers and in weather sealing of solar cells because the bond hermetically seals the surfaces together. 3 In our research group we use the process for sealing -reactors for catalyst characterization; 4 however for this application the high temperatures needed for successful anodic bonding may cause catalysts to sinter or otherwise lose activity. An example of this is Au-based catalysts, which are notorious for deactivating since activity is dependant on very small Au particle size.…”
mentioning
confidence: 99%