Co-rich Co-Cu and Co-Ni alloy electrodeposits were prepared by adding varying amounts of CuSO4 and NiSO4, respectively, to a CoSO4 bath under conditions favoring the hcp phase formation. According to various X-ray diffraction studies, in both the Co Cu and Co Ni systems an hcp phase formed exclusively up to about 2 at.% of the alloying element. Above this concentration, a significant fcc phase fraction appeared in Co-Cu and a minor fcc fraction in Co-Ni up to about 8 at.%. The measured lattice constants are analyzed in comparison with Vegard’s law. For Co rich Co-Ni alloys, the concentration dependence of the lattice parameters was found to follow Vegard’s law for both the hcp and fcc phases. For the Co rich Co-Cu alloys, the data indicate a positive deviation from Vegard’s law for both the hcp and fcc phase which is due to the excess mixing volume required for solid solution alloy formation of these immiscible elements . The MR data are discussed in the light of the observed phases and of the MR parameters reported in our previous work on the hcp and fcc phases of pure Co.