Anion-Induced Uniform and Robust Cathode–Electrolyte Interphase for Layered Metal Oxide Cathodes of Sodium Ion Batteries
Minli Wu,
Bei Zhang,
Yonghuang Ye
et al.
Abstract:Layer metal oxides demonstrate great commercial application potential in sodium-ion batteries, while their commercialization is extremely hampered by the unsatisfactory cycling performance caused by the irreversible phase transition and interfacial side reaction. Herein, trimethoxymethylsilane (TMSI) is introduced into electrolytes to construct an advanced cathode/ electrolyte interphase by tuning the solvation structure of anions. It is found that due to the stronger interaction between ClO 4 − and TMSI than … Show more
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