Anion-directed assembly: Framework conversion in dimensionality and photoluminescence

Highly Selective CO2 Uptake in Uninodal 6-Connected “mmo” Nets Based upon MO42– (M = Cr, Mo) Pillars

“…Such pillars are underexplored in MOMs. Indeed, there are just three reports concerning MoO 4 2– acting as a linker, whereas there are no examples reported for CrO 4 2– . [M(bpe) 2 (M′O 4 )] (M = Co, Ni; M′ = Mo, Cr) have been synthesized, structurally characterized, and evaluated in terms of their sorption behavior with respect to three industrially important gases: CO 2 , CH 4 , and N 2 .…”

Synthesis, Crystal Structure, and Properties of Two Zinc Tubular Coordination Polymers Based on Fluconazole

“…Besides, fluconazole could chelate to metal ions with endodentate nitrogen atoms (N 2 ) and alkoxo atom to form binuclear complex [15]. Another reason of the HFlu ligand proved to be a good candidate to construct polymeric structure is that it has several available donors/acceptors (2,4-difluorophenyl and hydroxyl groups) to form various weak interactions to stabilize the supramolecular frameworks [11][12][13][14][15][16][17][18][19][20][21].…”

Thiocyanate-induced conformational transformation of a flexible fluconazole ligand in Cd(II) coordination polymers

“…2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)propan-2-ol, HFlu] for rationally designing coordination polymers with fascinating structures (such as helix and dia-f net) and properties. [12][13][14][15] In these complexes, HFlu randomly adopts two typical conformations (Scheme 1), namely, anti-gauche (A-G) and anti-anti (A-A). In order to systematically explore the conformational variation of HFlu, six novel Cd(II) coordination polymers, namely {[Cd(HFlu) 2 (H 2 O) 2 ](ClO 4 ) 2 } n (1), {[Cd(HFlu) 3 -(NO 3 )] 2 $(NO 3 ) 2 $H 2 O} n (2), {[Cd(HFlu) 2 (SCN)](ClO 4 )} n (3), {[Cd(HFlu) 2 (SCN)](NO 3 )} n (4), {[Cd(HFlu) 2 Cl](SCN)} n (5) and {[Cd(HFlu) 2 (SCN) 2 ]$2H 2 O} n (6), have been synthesized and structurally characterized.…”