The reactions induced by 143 MeV 32S on 58Ni have been studied detecting discrete ?,-rays in coincidence with projectile-like fragments (PLF). Information on PLF excitation probability and sequential decay of target-like fragments (TLF) has been obtained. For the 28Si+ 62Zn outgoing channel at small energy loss (IQ[<20 MeV), both PLF and TLF data indicate that thermal equilibrium is not attained. The hypothesis of an equal excitation energy partition between the two reaction fragments does not describe properly experimental TLF data. A dependence of PLF excitation probability on the outgoing channel is found for the two final channels 32S+58Ni and 28Si+62Zn. The values of the spin alignment parameter Pzz, derived for PLF and TLF from measurements of ?,-rays anisotropy, are in disagreement with the expectations of the transport theory for dissipative collisions. PACS: 25.70.Lm.