“…The adjoint state method has been used successfully in a wide range of disciplines such as mathematical physics, geophysics, systems engineering, economics, constrained optimization, nuclear engineering, electrical engineering, meteorology, oceanography, hydrogeology, petroleum engineering, and seismology. In hydrogeology, the adjoint state method has been employed in many applications including interpretation of interference tests using geostastistical techniques (de Marsily et al, 1984), steady-state groundwater flow (Sykes et al, 1985;Wilson & Metcalfe, 1985), groundwater travel time uncertainty analysis (LaVenue et al, 1989), automated calibration of transmissivity fields (LaVenue et al, 1995;RamaRao et al, 1995), coupled nonlinear multiphase multicomponent flow (RamaRao & Mishra, 1996), modeling multidimensional groundwater flow (Clemo, 2007), adaptive multiscale parameterization of flow in unsaturated porous media (Hayek et al, 2008), transient groundwater flow in a bounded model domain (Lu & Vesselinov, 2015), fractured dual-porosity media (Delay et al, 2017;Fahs et al, 2014), and coupled surface water-groundwater modeling (RamaRao et al, 2017). However, few applications of the adjoint state method have been devoted to solute transport (e.g., Larbkich et al, 2014;Michalak & Kitanidis, 2004;Neupauer & Wilson, 1999, 2001Piasecki & Katopodes, 1997).…”