“…In contrast, the contour becomes a hexagon at E = ± t , indicating highly anisotropic electron energies. This in turn suggests that the electron group velocity, normal to the equal-energy contour, is highly anisotropic at E = ± t , having six preferred directions, as shown by the blue arrows in Figure c or d. At E = t , the group velocity can be calculated as v = 1 ℏ ∇ k E | E = t = true{ ± 3 a t ℏ ( 1 , 0 ) cos true( 3 2 a k y true) − 3 a t ℏ true( 1 2 , ± 3 2 true) sin ( 3 a k x ) At E = − t , the group velocity has the same expression as eq in the reverse directions, but they are filled states in the undoped graphene, which are not to be used. This anisotropic group velocity is the intrinsic property of graphene, independent of the calculation method (see Figure S2 in Supporting Information).…”