This decade‐long study from the INTERCONF programme addresses the data gap on ocean dynamics in the Southern Hemisphere. Focusing on the Brazil‐Malvinas Confluence (BMC), we investigated the effect of temperature differences between the warm Brazil Current (BC) and the cold Malvinas Current (MC) on water vapour in the marine atmospheric boundary layer (MABL). Our results show a clear distinction: warmer BMC waters have 32% more water vapour (2 kg·m−2 on average) compared to the MC. This highlights the direct link between ocean temperatures and atmospheric processes. Analysis of radiosonde data alongside satellite measurements showed better agreement over cooler waters with lower water vapour, leading to lower variability. This suggests less atmospheric turbulence and improved data compatibility, especially for satellite retrievals such as AIRS. Comparisons between reanalysis data (CFSR), satellite sounders (AIRS) and radiosondes (RS) showed consistent air temperature profiles, with average errors within the 10% threshold for satellite measurements. While capturing humidity variations remains a challenge, especially at high concentrations (indicated by higher mean squared error values), our study highlights the reliability of satellite data, particularly over the cold BMC region. This research highlights the importance of studying the interactions between ocean fronts and atmospheric phenomena for a complete picture of Southern Hemisphere ocean dynamics. It offers valuable insights for scientists across disciplines, providing a broad perspective on the results and their significance in different contexts.