Analysis of the thermal decomposition of azo-peroxyesters by Arrhenius-type and three-parameter equations

Hefczyc, Barbara; Siudyga, Tomasz; Zawadiak, Jan; Mianowski, A.

doi:10.1007/s10973-011-1538-1

Cited by 8 publications

(1 citation statement)

References 26 publications

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“…On the other hand, the value of the activation energy E a and E d can be determined from the curves of the dependence of the logarithm of the reaction rate (lnv) on the reciprocal of temperature (1/T), the socalled Arrhenius dependence [1]. However, the determined values of E a and E d by application of the traditional method is burdened with an error [2,3].…”

Section: Introductionmentioning

confidence: 99%

The inulin hydrolysis by recombinant exo-inulinases: determination the optimum temperatures and activation energies

Miłek

2021

J Therm Anal Calorim

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The advantages of recombinant enzymes over native include the control in a production environment, product purity and also high yield. The paper presents the determination the optimum temperatures and the activation energies for various origin recombinant exo-inulinases, among others from Aspergillus niger, A. awamori, Kluyveromyces marxianus and K. cicerisporus. The parameters were estimated based on the literature of the activity curves versus temperature for hydrolysis of inulin. It was assumed that both the hydrolysis reaction process and the deactivation process of recombinant exo-inulinase were first-order reactions by the enzyme concentration. A mathematical model describing the effect of temperature on recombinant exo-inulinase activity was used. Based on the comparison analysis, values of the activation energies $${E_{\rm a }}$$ E a were in the range from $${32.01 \pm 7.80}$$ 32.01 ± 7.80 to $${43.83 \pm 4.87}$$ 43.83 ± 4.87 kJ mol$$^{-1}$$ - 1 , the deactivation energies $${E_{\rm d }}$$ E d were in the range from $${83.93 \pm 4.82}$$ 83.93 ± 4.82 to $${352.44 \pm 14.26}$$ 352.44 ± 14.26 kJ mol$$^{-1}$$ - 1 and the optimum temperature $${T_{\rm opt }}$$ T opt were obtained in the range from $${318.91 \pm }$$ 318.91 ± 1.19 to $${328.76 \pm 0.25}$$ 328.76 ± 0.25 K.

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Section: Introductionmentioning

confidence: 99%