Improving Students' Ability to Understand Chemical Representations through the Implementation of a Web-Based E-Module on The Periodic System of Elements Materials. The study's objective was to improve learner's ability to understand chemical representation and learning outcomes by implementing web-based E-Module on periodic system of elements material. The type of research is development research (R & D) with a four steps model ( 4D) but only limited to the third stage namely develop stage. This research is a part of the development stage, namely limited trials using a quantitative descriptive method with the type was pre experimental with one group pretest-posttest design. This research was carried out in SMA Al-Islam Krian Sidoarjo region with the subject of the study, to be specific 18 students of class XI MIPA. The research data was obtained from the test of learning outcomes. Data was analysed by Wilcoxon test and N-gain. The result showed that the learner's ability to understand chemical representation was improve after using Web-Based E-Module proceeded with Wilcoxon test because the data was not normally distributed and obtained the Asymp. Sig. (2-tailed) value was 0,000. Based on N-gain score was obtained a range 0,69 -1 with medium or high criteria. Therefore, the implementation of web-based E-Module can be an alternative solution to improve the learner's ability to understand chemical representation.