Analysis of Reaction Kinetics of Carton Packaging Pyrolysis

Alvarenga, Larissa M.; Xavier, Thiago Padovani; Barrozo, M. A. S.; Bacelos, Marcelo Silveira; Lira, Taísa Shimosakai de

doi:10.1016/j.proeng.2012.07.401

Cited by 21 publications

(11 citation statements)

References 17 publications

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“…And the parallelism of lines was attributed to the similar kinetic behavior probably the same reaction mechanism was achieved. 33 The average activation energy of catalytic pyrolysis of DF was 192.7 kJ mol À1 , less than that (204.7 kJ mol À1 ) of noncatalytic pyrolysis, indicating that the average activation energy was reduced in the presence of the ZSM-5 catalyst. The trend of these lines could be divided into two groups: a ¼ 0.2-0.7 and a ¼ 0.8 based on their parallelism.…”

Section: Decomposition Kineticsmentioning

confidence: 85%

Thermal decomposition behavior and kinetics for pyrolysis and catalytic pyrolysis of Douglas fir

et al. 2018

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Section: Decomposition Kineticsmentioning

confidence: 85%

Thermal decomposition behavior and kinetics for pyrolysis and catalytic pyrolysis of Douglas fir

et al. 2018

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“…In this work, the Mastplosts method is used to determine the theoretical reaction mechanism. Parameters of this method can be evaluated on the basis of Equations (8)–(10):…”

Section: Resultsmentioning

confidence: 99%

Thermal conversion mechanism and thermodynamics of mixed oil in coal‐based needle coke production

Cheng

Xin

Gao

et al. 2019

Asia-Pacific J Chem Eng

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In this work, the kinetic and thermodynamic parameters of mixed oil during the process of thermal conversion are analyzed using a kinetic model and thermodynamic calculations combined with thermogravimetric analysis. On the basis of the Flynn-Wall-Ozawa kinetic model, the calculated activation energies change in the reaction progress of mixed oil. Additionally, the thermal conversion process can be divided into three stages. The reaction mechanism is the exponential law mode in the first phase, and the latter two stages belong to the random nucleation and subsequent growth model, but they have completely different ways of nucleation and crystal growth. During the whole thermal conversion of mixed oil, △H ≠ > 0, and it does not show that the thermal conversion of mixed oil is a completely endothermic process; △G ≠ > 0 and represents a nonspontaneous reaction; and the change of the △S ≠ value is the most complicated.

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“…According to reported studies, the parallelism of these lines is accredited to the same reaction mechanism and kinetic behavior. 63 For considered range of Note: T i : the ignition temperature, T f : burnout temperature, T 1 , T 2 : temperature at maximum weight loss rate of first peak and second peak.…”

Section: Kinetic Analysismentioning

confidence: 99%

Isoconversional nonisothermal kinetic analysis of municipal solid waste, refuse‐derived fuel, and coal

Azam

Ashraf

Jahromy

et al. 2020

Energy Science & Engineering

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Analysis of Reaction Kinetics of Carton Packaging Pyrolysis

Cited by 21 publications

References 17 publications

Thermal decomposition behavior and kinetics for pyrolysis and catalytic pyrolysis of Douglas fir

Thermal decomposition behavior and kinetics for pyrolysis and catalytic pyrolysis of Douglas fir

Thermal conversion mechanism and thermodynamics of mixed oil in coal‐based needle coke production

Isoconversional nonisothermal kinetic analysis of municipal solid waste, refuse‐derived fuel, and coal

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