1981
DOI: 10.1016/0022-2852(81)90182-x
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Analysis of phosphine absorption in the region 9–10 μm and high-resolution line-by-line simulation of the ν2 and ν4 bands

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Cited by 53 publications
(23 citation statements)
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“…Such transitions appear there as a doublet (l = ±1), whereas only one component is allowed from selection rules. We then retained only one transition as given in Table II of Tarrago et al (1981). H 2 -and He-broadened line halfwidths come from Levy et al (1993) for PH 3 , Brown & Peterson (1994) for NH 3 , and from a compilation by Linda Brown (private communication) for CH 4 .…”
Section: Discussionmentioning
confidence: 99%
“…Such transitions appear there as a doublet (l = ±1), whereas only one component is allowed from selection rules. We then retained only one transition as given in Table II of Tarrago et al (1981). H 2 -and He-broadened line halfwidths come from Levy et al (1993) for PH 3 , Brown & Peterson (1994) for NH 3 , and from a compilation by Linda Brown (private communication) for CH 4 .…”
Section: Discussionmentioning
confidence: 99%
“…As a consequence, spectroscopic effects and peculiarities should be particularly pronounced in the spectra of phosphine species. Both PH 3 and PD 3 and the partially deuterated PH 2 D species have been studied to some extent (see, e.g., (1,2,(6)(7)(8) and references cited therein). As to PHD 2 , this has been studied only in the microwave region (9)(10)(11)(12)(13), and recently in the far infrared regions (1).…”
Section: Introductionmentioning
confidence: 99%
“…In this contribution we present the results of the first highresolution vibration-rotation study of the three lowest-lying fundamentals ν 3 , ν 4 , and ν 6 . Infrared spectra in the 600-1160 cm −1 range of the PHD 2 molecule have been recorded with the Bruker IFS 120HR interferometer at Wuppertal with a resolution of 0.0023 cm −1 .…”
Section: Introductionmentioning
confidence: 99%
“…The matrix elements α λµ are determined by (see, for details, Ref. (12) [3] and lead to the secular equation [6] and . [7] Here r e N α are the Cartesian coordinates defining the equilibrium positions of the nuclei of the "mother" species in the molecule-fixed axis system.…”
Section: Isotopic Substitution Xhmentioning
confidence: 99%
“…Extensive studies of PH 3 spectra have been performed in the infrared region (see (6)(7)(8) and references cited therein). To the contrary, there are only two contributions devoted to the analysis of infrared spectra of the PH 2 D species: the bands ν 2 (a ), ν 3 (a ), ν 4 (a ), and ν 6 (a ) [ν 3a , ν 4a , ν 2 , and ν 4b in the notation of Refs.…”
Section: Introductionmentioning
confidence: 99%