The desire of humans to explore the universe is becoming stronger and stronger, which promotes the rapid development of aerospace technology and advanced aircrafts for the past few years. 1,2 A series of burgeoning high-technologies and great ideas, such as immigration to Mars and the star-link plan of the Space X company, are also demanding for more advanced aircrafts. Great aircrafts need great components. Thereinto, the radome is a crucial aerodynamic structural component, which is expected to transmit electromagnetic signals with minimum attenuation and also prevents radar communication systems from failure in harsh service environments. [3][4][5][6] Of the materials being considered for radome application, porous silicon nitride (Si 3 N 4 ) ceramic is one of the most promising candidates, because of its low density, low thermal conductivity, low thermal expansion coefficient, good thermal shock resistance, and great dielectric properties. 7-10 Unfortunately, porous Si 3 N 4 ceramic tend to absorb moisture from the atmosphere due to capillary force and high porosity. That will reduce its thermal insulation as well as deteriorate its dielectric properties. [11][12][13] The strategy for the preparation of dense coating on the porous Si 3 N 4 ceramic surface is an effervescent topic of scientific research. Many researchers have worked on this and received good results. [14][15][16] Wang and co-workers 17 fabricated