Atmospheric total suspended particulate aerosols were collected at the Gosan site of Jeju Island during 2011-2013, and their major water-soluble ionic and elemental species were analyzed in order to examine the chemical composition change and pollution characteristics change between Asian dust (AD) and non-Asian dust (NAD) periods. The comparison of the aerosol compositions showed that the concentrations of soil-originated species such as nss-Ca 2+ , Al, Fe, Ti, Mn, Ba, and Sr increased by as much as 4.5-18.6 times during the AD periods. Meanwhile, the concentrations of nss-SO 4 2− and NO 3 − , typical secondary aerosol species, increased 1.2 and 2.5 times, respectively. On the contrary, NH 4 + concentration decreased slightly during the AD periods, probably because of the neutralization reaction of acidic ammonium ion with basic calcium carbonate. A comparison of ion balances suggested that the carbonate contents in AD are likely much larger than those of NAD. Based on a cluster back-trajectory analysis, it was found that the concentrations of anthropogenic and soil-sourced components, such as nss-SO 4 2− , NO 3 − , NH 4 + , and nss-Ca 2+ , increased when an air mass moved into Jeju Island from the China continent, but decreased when an air mass moved from the North Pacific Ocean.