A secondary-ion mass spectroscopic study of a wurtzite GaN(0001) surface was conducted to test the operation of a novel surface-chemical analyzer using Ar 3+ (7.5 keV) and Ar 4+ (10 keV) ions. The analyzer allows us to measure the time of flight of a secondary ion simultaneously with the detection of the backscattered atom or ion that captured electrons from the surface atoms. A proton, CmH + n (m = 1-6 and n = 0-13), N + , Ga + , and GaN + ions were observed in the mass spectrum. The spectral width and profile were different between Ar 0 and Ar + -coincidence measurements.