“…According to a recent study, electricity generation from biogas in OECD countries grew from 3.7 TWh in 1990 to 78.8 TWh in 2015, making it the third fastest-growing renewable electricity source after wind and solar energy. Due to the advantages of AD, many research studies have sought to optimize the AD of MSW, including the interesting option of the codigestion process, which increases the load of biodegradable organic matter and produces a higher biogas yield. − Studies on AD of MSW have shown that the C:N ratio of this waste presents average values of 10:1, below the optimum for anaerobic digestion (25:1), while hydrogen production (HP) and methane production (MP) is reduced due to the washout of microorganisms, not to overloading. − Therefore, an increase in the loading rate employed in the AD process via the addition of readily biodegradable organic substances, such as glycerol, a major byproduct of biodiesel production, could constitute an ideal strategy. ,− Biodiesel manufacturing worldwide has gained in importance due to several factors: (i) the unavailability of fossil fuels due to demographics and political instability; (ii) modern methods of biodiesel production and new catalyst formulations producing higher biodiesel yields (iii) the breeding and cultivation of new varieties of oil crops with higher lipid yields (iv) an increase in the cultivation of inedible oilseed plants on waste land; (v) new engine designs that can use biodiesel and its admixtures as fuel; and (vi) stringent regulations to reduce GHG emissions. − Producing 100 kg of biodiesel yields approximately 10 kg of glycerin waste (GW) as a coproduct. Numerous sectors, such as the pharmaceutical, cosmetics, and food processing industries, use refined glycerol as a raw input material.…”