An XPS investigation of silver chloride coated ion-selective electrodes

Tailoring the Shape of Anisotropic Core–Shell Au–Ag Nanoparticles in Dimethyl Sulfoxide

“…The Cl 2p 3/2 peak at 197.6 eV representing the major component is assigned to adsorbed chloride ions on silver surface . The minor species whose Cl 2p 3/2 peak appears at 199.3 eV is likely resulting from the in situ X-ray photo-induced reduction of AgCl, as previously reported in the literature …”

“…54 The minor species whose Cl 2p 3/2 peak appears at 199.3 eV is likely resulting from the in situ X-ray photo-induced reduction of AgCl, as previously reported in the literature. 55 For core−shell particles synthesized via the DMSO-assisted silver growth, the signature of sulfur species was evidenced. Interestingly, the S 2p region shows binding energy peaks shifted by more than 3 eV toward lower binding energy from the expected values for oxidized sulfur (>165 eV).…”

Rapid fabrication of silver microplates under an oxidative etching environment consisting of O2/Cl−, NH4OH/H2O2, and H2O2

“…The XPS results show that AgCl was adsorbed on the basal planes of as-prepared AgMPls as indicated by the binding 6C). [58][59][60] In addition, the adsorption of the PVP-Ag + complex on Ag{100} facets promotes growth along the lateral side 10,36,46,[61][62][63][64] (Fig. S7 †).…”

Chemical Reaction of Polar Phthalocyanines on Silver: Chloroaluminum Phthalocyanine and Fluoroaluminum Phthalocyanine

“…The binding energy of the interface component of 197.7 eV is in good agreement to Cl 2p binding energies for chlorine reactively adsorbed on Ag(110) 34 and for AgCl electrodes. 35 We conclude therefore that the Cl atom is strongly interacting with the Ag substrate resulting in a break of the Al−Cl bond and in the formation of an Ag−Cl bond. As a consequence, bond formation may also occur between silver and the AlPc.…”