An Unprecedented 5‐Connected Self‐penetrated Cadmium(II) Coordination Polymer: Synthesis, Crystal Structure, and Luminescent Property

Zhang, Shuxin; Liu, Daofu

doi:10.1002/zaac.201300682

Cited by 5 publications

(3 citation statements)

References 27 publications

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“…The luminescent properties for complexes 1 and 2 are similar to those in Refs. 19,20. The emission bands of the carboxylate ligands originated from π*–n transition are weak, and it was considered that carboxylate ligands have no significant contribution to the fluorescence emission of complexes 1 and 2 in presence of the N‐donor ligand 23…”

Section: Resultsmentioning

confidence: 99%

Solvothermal Syntheses, Crystal Structures, and Luminescent Properties of Two Coordination Polymers with Different Interpenetrated Diamond Topology

Deng¹

2015

Zeitschrift anorg allge chemie

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Two coordination polymers, namely, {[Zn(bpea) (bmp)]·H2O}n (1) and {[Ni(bpea)(bimb)]·DMF}n (2) [H2bpea = biphenylethene‐4,4′‐dicarboxylate, bmp = 1,4‐bis(2‐methylimidazol‐3‐ium‐1‐yl)biphenyl and bimb = 1,4‐bis(1‐imidazol‐yl)‐2,5‐dimethyl benzene], were synthesized under solvothermal conditions with mixed organic ligands. Single crystal X‐ray diffraction reveals that complex 1 features a three‐dimensional (3D) structure with a sixfold interpenetrating dia net. Complex 2 shows a 3D fivefold interpenetrating dia topology. Furthermore, the solid state luminescent properties of complexes 1 and 2 were investigated at room temperature.

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Section: Resultsmentioning

confidence: 99%

Solvothermal Syntheses, Crystal Structures, and Luminescent Properties of Two Coordination Polymers with Different Interpenetrated Diamond Topology

Deng¹

2015

Zeitschrift anorg allge chemie

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“…The free ligands bib and bimb exhibit intense emission bands at 456 and 408 nm, respectively [34,35]. The emission bands of the free ligands may be assigned to π*-π or π*-n transitions [36].…”

Section: Luminescent Propertiesmentioning

confidence: 98%

Syntheses, crystal structures and luminescent properties of two new Zn(II) coordination polymers based on a dicarboxylate and different imidazole-containing ligands

Feng

Chen

Xiang

2016

Journal of Coordination Chemistry

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To investigate the effect of different imidazole-containing ligands on the structure of coordination polymers, two new Zn(II) coordination polymers based on 1,4-cyclohexanedicarboxylic acid (H 2 cda) and two different imidazole-containing ligands, [Zn(cda)(bib) 0.5 ] n (1) and [Zn(cda)(bmib) 0.5 ] n (2) (bib = 1,4-bis(imidazol-1-yl)benzene and bmib = 1,4-bis(2-methylimidazol-3-ium-yl)benzene), have been synthesized and characterized by singlecrystal X-ray diffraction. Complex 1 shows a 3-D structure with point symbol (4.8 2 .10 3 ).(4.8 2 ). Complex 2 displays a 2-D layer structure with an -AB-stacking sequence. ARTICLE HISTORY

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“…Metal–organic frameworks (MOFs) have a variety of fascinating architectures, at the same time, they have extensive application prospects as the hybrid functional materials in luminescence, chemical separation, magnetism, gas storage, heterocatalysis, and so on [4–7]. Therefore, reasonable design along with creation of the MOFs is the present research hotspot.…”

Section: Introductionmentioning

confidence: 99%

Solvothermal synthesis of a new heterometallic Cd–Ba compound based on terephthalic acid: Catalytic property and therapeutic effect on diabetes

Zhang

Ying

et al. 2022

Micro & Nano Letters

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Presented is a new heterometallic compound, namely [Cd2Ba2(pdc)4(H2O)4(DMA)2]}n·n(H2O) (1, H2pdc = terephthalic acid, DMA is N, N′‐dimethylacetamide), which was created with the solvothermal reaction. The architectural analysis of X‐ray indicated that the 1 reveals a three‐dimensional skeleton according to one‐dimensional infinite chains. After removal of the free along with coordinated solvent molecules, it contains 49.8% solvent‐accessible volume and unsaturated coordination sites. The solvent‐free form of 1 exhibits excellent catalytic effect for the addition reaction between diethylzinc and benzaldehyde. Its therapeutic effect and mechanism exploration on diabetes was conducted in this present research. Firstly, the abundance of intestinal flora in the gut was detected with real time RT‐PCR assay. Besides, the measurement of the levels of sugar was conducted with blood glucose meter in the T2DM animal after compound treatment. The cytotoxicity of the 1 was evaluated with CCK‐8 assay.

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An Unprecedented 5‐Connected Self‐penetrated Cadmium(II) Coordination Polymer: Synthesis, Crystal Structure, and Luminescent Property

Cited by 5 publications

References 27 publications

Solvothermal Syntheses, Crystal Structures, and Luminescent Properties of Two Coordination Polymers with Different Interpenetrated Diamond Topology

Solvothermal Syntheses, Crystal Structures, and Luminescent Properties of Two Coordination Polymers with Different Interpenetrated Diamond Topology

Syntheses, crystal structures and luminescent properties of two new Zn(II) coordination polymers based on a dicarboxylate and different imidazole-containing ligands

Solvothermal synthesis of a new heterometallic Cd–Ba compound based on terephthalic acid: Catalytic property and therapeutic effect on diabetes

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